Adsorptive remediation of cobalt oxide nanoparticles by magnetized α-cellulose fibers from waste paper biomass.

Bioresour Technol

Department of Biological and Environmental Science, College of Life Science and Biotechnology, Dongguk University-Seoul, 32, Dongguk-ro, Ilsandong-gu, Goyang-si, Gyonggido 10326, Republic of Korea. Electronic address:

Published: February 2019

Remediation of engineered-nanomaterials is an up-coming major environmental concern. This study demonstrates adsorptive-remediation of cobalt oxide nanoparticles (CoO NPs) from the water. The α-cellulose-fibers were extracted from waste-paper biomass (WP-αCFs) and magnetized with FeO NPs (M-WP-αCFs). The XRD, FT-IR, and TGA were performed for detailed characterization of the newly developed bioadsorbent. The M-WP-αCFs was then applied for adsorptive remediation of CoO NPs. The adsorptive kinetics of CoO NPs adsorption onto the M-WP-αCFs reveals the pseudo-second-order model. The various adsorption isotherm studies revealed Langmuir is a best-fit isotherm. A prominently high adsorption capacity q (1567 mg/g) corroborated extraordinary adsorptive potential of M-WP-αCFs. Furthermore, CoO NPs were adsorbed onto M-WP-αCFs were analyzed by the XPS, VSM, and TEM. Therefore, this study gave rise WP biomass extracted and rapidly-separable nano-biocomposite of 'M-WP-αCFs' with a high-capacity for CoO NPs remediation and can be further applied in remediation of several other engineered-nanomaterials.

Download full-text PDF

Source
http://dx.doi.org/10.1016/j.biortech.2018.11.041DOI Listing

Publication Analysis

Top Keywords

coo nps
20
adsorptive remediation
8
cobalt oxide
8
oxide nanoparticles
8
remediation engineered-nanomaterials
8
nps
6
coo
5
m-wp-αcfs
5
adsorptive
4
remediation cobalt
4

Similar Publications

Mineral-Mediated Epitaxial Growth of CoO Nanoparticles for Efficient Electrochemical HO Activation.

ACS Nano

December 2024

Engineering Research Center of Nano-Geomaterials of Ministry of Education, China University of Geosciences, Wuhan 430074, China.

Solution-phase epitaxy is a versatile method to synthesize functional nanomaterials with customized properties, where supports play a central role as they not only serve as nucleation templates but also greatly affect the local electronic structures. However, developing functional supports remains a great challenge. Herein, inspired by the commonly observed epitaxy of minerals in the natural environment, we report using calcination-modified kaolinite as the support for the epitaxial growth of hexagonal CoO nanoparticles (-CoO NPs), which enables over 40 times higher mass-specific activity toward HO electrochemical activation than the counterpart without the support.

View Article and Find Full Text PDF

Synthesis and Local Characterization of CoO Nanoparticles in Distinct Phases: Unveiling Polymorphic Structures.

ACS Omega

October 2024

Faculdade de Ciências Exatas e Tecnologia, Universidade Federal do Pará (UFPA), Abaetetuba, Pará 684440-000, Brazil.

Article Synopsis
  • - The study focuses on cobalt oxide nanoparticles (CoO-NPs), which exhibit unique catalytic and magnetic properties, making them valuable for applications like catalysts, drug delivery, and sensors.
  • - Researchers explored the synthesis and local characterization of CoO-NPs in two crystal structures—rock-salt cubic (fcc-CoO) and Wurtzite (hcp-CoO)—using different ligands (oleylamine and oleic acid) to control their properties.
  • - Techniques such as X-ray diffraction (XRD) and Raman spectroscopy confirmed the successful synthesis of both phases, with the better morphological control observed in nanoparticles produced using a combination of the ligands.
View Article and Find Full Text PDF

The current work is the first ever report on the functionalization of CoO nanoparticles (NPs) using the bio active constituents of Abies pindrow Royle (A.pindrow) leaves. An efficient phytochemical extraction method was determined by comparing different extraction strategies for extracting the biologically active compounds of A.

View Article and Find Full Text PDF

Novel Synthesis and Biophysical Characterization of Zinc Oxide Nanoparticles Using Virgin Coconut Oil.

ACS Omega

September 2024

Crystal Growth and Nano-Science Research Centre, Department of Physics, Government College (A), Rajamahendravaram, Andhra Pradesh 533105, India.

One of the primary concerns in the field of green synthesis of nanoparticles (NPs) utilizing plant materials is the scarcity of high purity, challenges in achieving large-scale production, and limited global accessibility. Hygienic preparation and safe storage of plant extracts are also considerable challenges in this field. So, an investigation was started to overcome these limitations.

View Article and Find Full Text PDF

This research describes the methodology for synthesizing zinc oxide nanoparticles (ZnO-NPs). It demonstrates a unique, cost-effective, and non-toxic chemical technique for producing ZnO-NPs using the precipitation method with NaOH as reducing and capping agents. The formed nanoparticles have been characterized and analyzed using numerous techniques such as; Fluorescence emission spectroscopy (FL), X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy-dispersive X-ray Spectroscopy (EDX), ultraviolet-visible optical absorption (UV-Vis), Fourier transform infrared spectroscopy (FTIR), and Thermal gravimetric analysis (TGA).

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!