Organoboron "ate" complexes undergo a net vinyl insertion reaction to give 1,1-disubstituted alkenyl boronic esters when treated with stoichiometric allyl acetate and a palladium catalyst. Reactions that employ vinyllithium afforded good to excellent yields after one hour, while reactions that employ vinylmagnesium chloride furnished modest to good yields after 18 hours.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6414219 | PMC |
| http://dx.doi.org/10.1002/anie.201811782 | DOI Listing |
Publication Analysis
Top Keywords
reactions employ
8
vinylidenation organoboronic
4
organoboronic esters
4
esters enabled
4
enabled pd-catalyzed
4
pd-catalyzed metallate
4
metallate shift
4
shift organoboron
4
organoboron "ate"
4
"ate" complexes
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!