Single-molecule magnet behaviour in a Dy(iii) pentagonal bipyramidal complex with a quasi-linear Cl-Dy-Cl sequence.

Dalton Trans

Institut Charles Gerhardt, Equipe Ingénierie Moléculaire et Nano-Objets, Université de Montpellier, ENSCM, CNRS, Place Eugène Bataillon, 34095 Montpellier Cedex 5, France.

Published: December 2018

We report the synthesis and magnetic investigation of a dysprosium pentagonal bipyramidal complex [Dy(THF)5Cl2][BPh4] (1) exhibiting a linear Cl-Dy-Cl sequence suitable for providing a coordination environment allowing a zero-field slow relaxation of the magnetization. Besides, the complex also shows dual luminescence originating from [BPh4]- and Dy3+.

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Source
http://dx.doi.org/10.1039/c8dt04098bDOI Listing

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