The water cycle at subduction zones remains poorly understood, although subduction is the only mechanism for water transport deep into Earth. Previous estimates of water flux exhibit large variations in the amount of water that is subducted deeper than 100 kilometres. The main source of uncertainty in these calculations is the initial water content of the subducting uppermost mantle. Previous active-source seismic studies suggest that the subducting slab may be pervasively hydrated in the plate-bending region near the oceanic trench. However, these studies do not constrain the depth extent of hydration and most investigate young incoming plates, leaving subduction-zone water budgets for old subducting plates uncertain. Here we present seismic images of the crust and uppermost mantle around the central Mariana trench derived from Rayleigh-wave analysis of broadband ocean-bottom seismic data. These images show that the low mantle velocities that result from mantle hydration extend roughly 24 kilometres beneath the Moho discontinuity. Combined with estimates of subducting crustal water, these results indicate that at least 4.3 times more water subducts than previously calculated for this region. If other old, cold subducting slabs contain correspondingly thick layers of hydrous mantle, as suggested by the similarity of incoming plate faulting across old, cold subducting slabs, then estimates of the global water flux into the mantle at depths greater than 100 kilometres must be increased by a factor of about three compared to previous estimates. Because a long-term net influx of water to the deep interior of Earth is inconsistent with the geological record, estimates of water expelled at volcanic arcs and backarc basins probably also need to be revised upwards.
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http://dx.doi.org/10.1038/s41586-018-0655-4 | DOI Listing |
Biotechnol Biofuels Bioprod
January 2025
Institute for Pulsed Power and Microwave Technology (IHM), Karlsruhe Institute of Technology (KIT), Eggenstein-Leopoldshafen, Germany.
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View Article and Find Full Text PDFBMC Oral Health
January 2025
Department of Dental Science, Damascus University, Damascus, Syria.
Background: The smear layer formed during root canal instrumentation negatively affects root canal irrigation activity, which in turn can affect the treatment prognosis of endodontic treatment.
Aim: The aim of this study is to compare the efficiency of smear layer and debris removal in root canals using different irrigation protocols using scanning electron microscopy (SEM).
Materials And Methods: The quality of smear layer removal throughout the root canal was assessed in 30 intact extracted teeth divided into 3 groups according to the irrigation protocol: Group 1: 3% sodium hypochlorite (NaOCL) alternately with 17% ethylenediaminetetraacetic acetate (EDTA) was used.
ACS Appl Mater Interfaces
January 2025
Key Laboratory of Bio-based Polymeric Materials Technology and Application of Zhejiang Province, Ningbo Institute of Materials Technology & Engineering, Chinese Academy of Sciences, 1219 Zhongguan West Road, Ningbo 315201, China.
2,5-Furandicarboxylic acid (FDCA) is one of the top selected value-added chemicals, which can be obtained by the aerobic oxidation of 2,5-bis(hydroxymethyl)furfural (BHMF) over a Pd-based catalyst. However, the elucidation of the reaction mechanism was hindered by its rapid kinetics. Herein, employing the density functional theory (DFT) calculations, we delve into the detailed reaction pathways of the BHMF oxidation into FDCA over Pd(111) and PdH(111) identifying the rate-determining steps.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
January 2025
CESAM & Department of Biology, University of Aveiro, 3810-193, Aveiro, Portugal.
Worldwide, many coastal freshwater ecosystems suffer from seawater intrusion. In addition to this stressor, it is likely that the biota inhabiting these ecosystems will also need to deal with climate change-related temperature fluctuations. The resilience of populations to long-term exposure to these stressors will depend on their genetic diversity, a key for their adaptation to changing environments.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
January 2025
Division of Marine and Freshwater Biology, Department of Zoology, Faculty of Science, The Maharaja Sayajirao University of Baroda, Vadodara, Gujarat, India.
This study delves into the Molluscan diversity along the Gujarat coast, India, focusing on the distribution and habitat suitability of four key species: Cerithium caeruleum, Lunella coronata, Peronia verruculata, and Trochus radiatus. Utilizing species distribution models (SDMs) integrated with machine learning algorithms, we assessed the impact of environmental variables on the distribution patterns of these molluscs. Our findings reveal a nuanced understanding of habitat preferences, highlighting the critical roles of salinity, chlorophyll concentration, and water temperature.
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