AI Article Synopsis
- The dinuclear mesocate [Fe2L3](BF4)4 is used to create a microporous material with a complex 3D framework.
- Extensive noncovalent interactions in the solid-state help form microporous channels that allow guest molecules to enter.
- The material shows a strong preference for adsorbing CO2 over N2, indicating its potential for gas separation applications.
Article Abstract
The dinuclear mesocate [Fe2L3](BF4)4, 1, is a supramolecular building block for a microporous material. Structural analysis reveals that extensive noncovalent interactions in the solid state generate a 3D framework with microporous channels. These channels are permanently accessible to incoming guest molecules and adsorption isotherms demonstrate that the material has a high selectivity for CO2 over N2.
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| http://dx.doi.org/10.1039/c8cc07227b | DOI Listing |
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