Microphysical and kinematic characteristics of two storm populations, based on their macroscale charge structures, are investigated in an effort to increase our understanding of the processes that lead to anomalous (or inverted charge) structures. Nine normal polarity cases (mid-level negative charge) with dual-Doppler and polarimetric coverage that occurred in northern Alabama, and six anomalous polarity cases (mid-level positive charge) that occurred in northeastern Colorado are included in this study. The results show that even though anomalous polarity storms formed in environments with similar instability, they had significantly larger and stronger updrafts. Moreover, the anomalous polarity storms evidently have more robust mixed-phase microphysics, based on a variety of metrics. Anomalous polarity storms in Colorado have much higher cloud base heights and shallower warm cloud depths in this study, leading us to hypothesize that anomalous polarity storms have lower amounts of dilution and entrainment. We infer positively charged graupel, and therefore high supercooled water contents, in the mid-levels of the anomalous storms based on the relationship between colocations of graupel and inferred positive charge from Lightning Mapping Array data. Using representative updraft speeds and warm cloud depths, the time required for a parcel to traverse from cloud base to the freezing level was estimated for each storm observation. We suggest this metric is the key discriminator between the two storm populations and leads us to hypothesize that it strongly influences the amount of supercooled water and the probability of positive charge in the midlevels, leading to an anomalous charge structure.
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http://dx.doi.org/10.1029/2017JD027540 | DOI Listing |
Phys Chem Chem Phys
January 2025
College of Sciences, Northeastern University, Shenyang, 110819, China.
In this work, using first-principles calculations, we predict a promising class of two-dimensional ferromagnetic semiconductors, namely Janus PrXY (X ≠ Y = Cl, Br, I) monolayers. Through first-principles calculations, we found that PrXY monolayers have excellent dynamic and thermal stability, and their band structures, influenced by magnetic exchange and spin-orbital coupling, exhibit significant valley polarization. Between and - valleys, the Berry curvature values are opposite to each other, resulting in the anomalous valley Hall effect.
View Article and Find Full Text PDFSci Rep
January 2025
Department of Applied Physics, School of Engineering Sciences, KTH Royal Institute of Technology, AlbaNova University Center, SE-10691, Stockholm, Sweden.
Non-trivial band topology along with magnetism leads to different novel quantum phases. When time-reversal symmetry is broken in three-dimensional topological insulators (TIs) through, e.g.
View Article and Find Full Text PDFPhys Chem Chem Phys
January 2025
School of Physics and Electrical Engineering, Hubei Key Laboratory of Low Dimensional Optoelectronic Materials and Devices, Hubei Longzhong Laboratory, Hubei University of Arts and Science, Xiangyang, Hubei, 441053, China.
Exploring valleytronics in two-dimensional materials is of great significance for the development of advanced information devices. In this study, we investigate the valley polarization and electronic properties of V-doped 2H-phase Janus MoSeTe by using first-principles calculations. Our results reveal a remarkable valley spin splitting up to 60 meV, driven by the breaking of time-reversal symmetry due to the magnetic effect of V 3d orbitals.
View Article and Find Full Text PDFAdv Sci (Weinh)
January 2025
State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, P. R. China.
Circularly Polarized Light (CPL)-dependent anomalous photovoltaic effect (APVE), characterized by light helicity-manipulated steady photocurrent and above-bandgap photovoltage, has demonstrated significant potential in the fields of photoelectronic and photovoltaics. However, exploiting CPL-dependent APVE in chiral hybrid perovskites, a promising family with intrinsic chiroptical activity and non-centrosymmetric structure, remains challenging. Here, leveraging the flexible structural design of chiral alternating cations intercalation-type perovskites, CPL-dependent APV, for the first time, is achieved in chiral perovskites.
View Article and Find Full Text PDFJ Phys Chem A
January 2025
Department of Chemistry, Gottwald Center for the Sciences, University of Richmond, Richmond, Virginia 23173, United States.
The propensities for sigma hole bonding by halogen atoms bonded to central atoms below period 2 in the periodic table remain to be systematically examined. Using iodine as our reference halogen atom, a comprehensive analysis of the tendencies for halogen and other forms of significant sigma hole bonding by simple compounds of main group atoms from H to At is accomplished. An examination of the structure and bonding of complexes formed by those iodine-substituted main group compounds and sigma donating bases (ammonia and trimethylamine) is performed to probe the viability of halogen bonding by heavy main group RM-I compounds in particular, given the historic focus on period 2.
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