Biomass-Mediated Synthesis of Cu-Doped TiO Nanoparticles for Improved-Performance Lithium-Ion Batteries.

Pure TiO and Cu-doped TiO nanoparticles are synthesized by the biomediated green approach using the Bengal gram bean extract. The extract containing biomolecules acts as capping agent, which helps to control the size of nanoparticles and inhibit the agglomeration of particles. Copper is doped in TiO to enhance the electronic conductivity of TiO and its electrochemical performance. The Cu-doped TiO nanoparticle-based anode shows high specific capacitance, good cycling stability, and rate capability performance for its envisaged application in lithium-ion battery. Among pure TiO, 3% Cu-doped TiO, and 7% Cu-doped TiO anode, the latter shows the highest capacity of 250 mAh g (97.6% capacity retention) after 100 cycles and more than 99% of coulombic efficiency at 0.5 A g current density. The improved electrochemical performance in the 7% Cu-doped TiO is attributed to the synergetic effect between copper and titania. The results reveal that Cu-doped TiO nanoparticles might be contributing to the enhanced electronic conductivity, providing an efficient pathway for fast electron transfer.