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An enantioselective synthesis of the core unit of the non-nucleoside reverse transcriptase inhibitor taurospongin A. | LitMetric
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An enantioselective synthesis of the core unit of the non-nucleoside reverse transcriptase inhibitor taurospongin A.

Arun K Ghosh Hui Lei

Tetrahedron Asymmetry

Department of Chemistry, University of Illinois at Chicago, 845 West Taylor Street, Chicago, IL 60607, USA.

Published: March 2003

An enantioselective formal synthesis of taurospongin A has been achieved. The key steps involve chelation-controlled reductions of β-ketosulfoxide and β-hydroxy ketone intermediates and Sharpless asymmetric epoxidation to construct the tertiary alcohol stereoselectively.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6211187PMC
http://dx.doi.org/10.1016/S0957-4166(03)00040-5DOI Listing

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