In this study, the kraft lignin/cubic boron nitride hybrid materials have been obtained and characterized for the first time. The effectiveness of the combination of lignin and boron nitride was evaluated on the basis of Fourier transform infrared spectroscopy. Furthermore, it was confirmed that the addition of cubic boron nitride (cBN) improved the thermal stability of the inorganic-organic material. Upswing in thermal properties allowed to apply the prepared materials in preparation of model abrasive composites. Beneficial influence of the lignin/cBN filler was also proven by a noticeable decrease in the amount of harmful phenol released from the compositions during headspace gas chromatography analysis. Mechanical properties of the lignin/boron nitride hybrids and resin systems were investigated by the three-point flexural test. The obtained results show that the used additives can be promising materials for abrasive tools combining the good properties of lignin as a plasticizer and of cubic boron nitride as a filler which improves the thermal and mechanical properties of finished products and, at the same time, limits the negative impact on human health and environment.
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http://dx.doi.org/10.1016/j.ijbiomac.2018.10.163 | DOI Listing |
Polymers (Basel)
January 2025
Faculty of Mechanics, University Politehnica of Timisoara, Piata Victoriei 2, 300006 Timisoara, Romania.
This study investigated silicone composites with distributed boron nitride platelets and carbon microfibers that are oriented electrically. The process involved homogenizing and dispersing nano/microparticles in the liquid polymer, aligning the particles with DC and AC electric fields, and curing the composite with IR radiation to trap particles within chains. This innovative concept utilized two fields to align particles, improving the even distribution of carbon microfibers among BN in the chains.
View Article and Find Full Text PDFMaterials (Basel)
January 2025
Faculty of Materials Science and Ceramics, AGH University of Krakow, 30-059 Krakow, Poland.
This paper presents a comprehensive study of two tool materials designed for the machining of Inconel 718 superalloy, produced through two distinct sintering techniques: High Pressure-High Temperature (HPHT) sintering and Spark Plasma Sintering (SPS). The first composite (marked as BNT), composed of 65 vol% cubic boron nitride (cBN), was sintered from the cBN-TiN-TiSiC system using the HPHT technique at a pressure of 7.7 GPa.
View Article and Find Full Text PDFMicromachines (Basel)
January 2025
Jilin Province Product Quality Supervision and Inspection Institute, Changchun 130103, China.
Observing the intricate microstructure changes in abrasive flow machining with traditional experimental methods is difficult. Molecular dynamics simulations are used to look at the process of abrasive flow processing from a microscopic scale in this work. A molecular dynamics model for micro-cutting a single crystal γ-TiAl alloy with a rough surface in a fluid medium environment is constructed, which is more realistic.
View Article and Find Full Text PDFAdv Sci (Weinh)
January 2025
School of Physical Science and Technology, ShanghaiTech Laboratory for Topological Physics, ShanghaiTech University, Shanghai, 201210, P. R. China.
Over the years, great efforts have been devoted in introducing a sizable and tunable band gap in graphene for its potential application in next-generation electronic devices. The primary challenge in modulating this gap has been the absence of a direct method for observing changes of the band gap in momentum space. In this study, advanced spatial- and angle-resolved photoemission spectroscopy technique is employed to directly visualize the gap formation in bilayer graphene, modulated by both displacement fields and moiré potentials.
View Article and Find Full Text PDFNature
January 2025
Department of Physics, Massachusetts Institute of Technology, Cambridge, MA, USA.
Electrons in topological flat bands can form new topological states driven by correlation effects. The pentalayer rhombohedral graphene/hexagonal boron nitride (hBN) moiré superlattice was shown to host fractional quantum anomalous Hall effect (FQAHE) at approximately 400 mK (ref. ), triggering discussions around the underlying mechanism and role of moiré effects.
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