We present a molecular dynamics study of the effects of confinement on the lubrication and flow properties of ionic liquids. We use a coarse-grained salt model description of ionic liquid as a lubricant confined between finite solid plates and subjected to two dynamic regimes: shear and cyclic loading. The impact of confinement on the ion arrangement and mechanical response of the system has been studied in detail and compared to static and bulk properties. The results have revealed that the wall slip has a profound influence on the force built-up as a response to mechanical deformation and that at the same time in the dynamic regime interaction with the walls represents a principal driving force governing the behaviour of ionic liquid in the gap. We also observe a transition from a dense liquid to an ordered and potentially solidified state of the ionic liquid taking place under variable normal loads and under shear.
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http://dx.doi.org/10.1140/epje/i2018-11740-6 | DOI Listing |
Pharmaceutics
December 2024
Faculty of Pharmaceutical Sciences, Josai International University, 1 Gumyo, Togane 283-8555, Chiba, Japan.
: Laurocapram (Azone) attracted attention 40 years ago as a compound with the highest skin-penetration-enhancing effect at that time; however, its development was shelved due to strong skin irritation. We had already prepared and tested an ante-enhancer (IL-Azone), an ionic liquid (IL) with a similar structure to Azone, consisting of ε-caprolactam and myristic acid, as an enhancer candidate that maintains the high skin-penetration-enhancing effect of Azone with low skin irritation. In the present study, fatty acids with different carbon numbers (caprylic acid: C8, capric acid: C10, lauric acid: C12, myristic acid: C14, and oleic acid: C18:1) were selected and used with ε-caprolactam to prepare various IL-Azones in the search for a more effective IL-Azone.
View Article and Find Full Text PDFPlants (Basel)
January 2025
Research Faculty of Agriculture, Hokkaido University, Sapporo 060-8589, Japan.
This study explores the effects of a subcritical seawater treatment (SST) on buckwheat waste (BW), and the use of the hydrolysate as a liquid fertilizer to improve the growth of lettuce ( L.). Three temperature treatments (110 °C, 170 °C, 230 °C) were used for the SST, and the ionic composition in the seawater achieved the depolymerization and degradation of BW.
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January 2025
Guangdong Provincial Key Laboratory of Fuel Cell Technology, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510641, China.
Solid polymer electrolytes (SPEs) have attracted much attention due to their excellent flexibility, strong interfacial adhesion, and good processibility. However, the poor interfacial contact between the separate solid polymer electrolytes and electrodes leads to large interfacial impedance and, thus, hinders Li transport. In this work, an ionic liquid-modified comb-like crosslinked network composite solid-state electrolyte with an integrated electrolyte/cathode structure is prepared by in situ ultraviolet (UV) photopolymerization.
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January 2025
CNR-STIIMA, Italian National Research Council, Institute of Intelligent Industrial Technologies and Systems for Advanced Manufacturing, 13900 Biella, Italy.
Thanks to their unique physicochemical properties, ionic liquids (ILs) have moved from niche academic interest to critical components in various industrial applications. The textile industry, facing significant environmental and economic pressures, has begun to explore ILs as sustainable alternatives to traditional solvents and chemicals. This review summarizes research on the use of ILs in various textile processes, including dyeing, finishing, and fiber recycling, where their high thermal stability, tunable solubility, and low volatility are exploited to reduce resource consumption and environmental impact.
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January 2025
Department of Chemical Engineering, Louisiana Tech University, 600 Dan Reneau Drive, P.O. Box 10348, Ruston, LA 71272, USA.
Adequate water supplies are crucial for missions to the Moon, since water is essential for astronauts' health. Ionic liquids (ILs) have been investigated for processing metal oxides, the main components of lunar regolith, to separate oxygen and metals. The IL must be diluted in the process.
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