Magneto-Optical Properties of the Magnetite-Graphene Oxide Composites in Organic Solvents.

ACS Appl Mater Interfaces

Laboratory for Advanced Carbon Nanomaterials , Kazan Federal University, Kremlyovskaya Street 18 , Kazan 420008 , Russian Federation.

Published: November 2018

AI Article Synopsis

  • Graphene oxide (GO) aqueous solutions can form liquid crystals that respond to electric fields, but are generally unresponsive to magnetic fields due to their diamagnetic nature and poor solubility in organic solvents.
  • This study successfully combines GO with oleate-protected magnetite nanoparticles to create stable colloid solutions in isopropanol-chloroform mixtures, allowing for improved responsiveness to magnetic fields.
  • The adjustable structure and properties of these composite solutions allow for manipulation of optical transmission and light scattering, which could lead to innovative applications like magneto-optical switches, density-gradient materials, and micromotors.

Article Abstract

Graphene oxide (GO) aqueous solutions are known to form liquid crystals that can switch in electric fields. Magnetic fields as external stimuli are inefficient toward GO because of its diamagnetic properties, and GO is known to be insoluble in most of the organic solvents. In this study, composites of GO with oleate-protected magnetite nanoparticles were prepared as stable colloid solutions in the mixed isopropanol-chloroform solvents. The structure of the composite particles and the optical properties of their solutions can be controlled by the ratio of the mixing parent components. The as-prepared solutions are highly responsive to external magnetic field. As the consequence, the optical transmission and the direction of light scattering can be efficiently manipulated. These systems pave the way for fabricating functional materials, such as magneto-optical switches, density-gradient materials, and micromotors. Solubility in nonpolar organic solvents broadens the scope of their potential applications.

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Source
http://dx.doi.org/10.1021/acsami.8b15129DOI Listing

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