Fullerene Aggregation in Thin Films of Polymer Blends for Solar Cell Applications.

We report on the effects of the film morphology on the fluorescence spectra for a thin film including a quinoxaline-based co-polymer (TQ1) and a fullerene derivative ([6,6]-phenyl-C-butyric acid methyl ester-PCBM). The ratio between the polymer and the fullerene derivative, as well as the processing solvent, were varied. Besides the main emission peak at 700 nm in the fluorescence spectra of thin films of this phase-separated blend, a broad emission band is observed with a maximum at 520⁻550 nm. The intensity of this emission band decreases with an increasing degree of mixing in the film and becomes most prominent in thicker films, films with high PCBM content, and films that were spin-coated from solvents with lower PCBM solubility. We assign this emission band to aggregated PCBM.