Tunability of fluorescent metal-organic frameworks through dynamic spacer installation with multivariate fluorophores.

Chem Commun (Camb)

MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275, China.

Published: December 2018

Through dynamic spacer installation, five fluorescent metal-organic frameworks (MOFs) have been constructed based on a proto-MOF LIFM-28 and multivariate ligands as fluorophores. The emissions are tunable via insertion of fluorescent ligands, demonstrating a versatile approach for luminescence tuning by virtue of dynamic spacer installation using swing-role MOFs.

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Source
http://dx.doi.org/10.1039/c8cc07441kDOI Listing

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