Semireduction of Alkynes Using Formic Acid with Reusable Pd-Catalysts.

J Org Chem

Department of Chemistry, Faculty of Science , Tokyo University of Science, 1-3 Kagurazaka , Shinjuku-ku, Tokyo 162-8601 , Japan.

Published: November 2018

The treatment of PdCl with KCO and HCOH in dioxane gives black precipitates, which are an effective catalyst for the semireduction of alkynes to alkenes using formic acid as a reductant. Even 0.05 mol % Pd promoted the reduction reaction of tolane in high yield with high selectivity.

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http://dx.doi.org/10.1021/acs.joc.8b02169DOI Listing

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