The new phase CoScSbO and NiCoScSbO solid solutions adopt the polar NiTeO-type structure and order magnetically below 60 K. A series of long-period lock-in [0 0 1/3n] spin structures with n = 5, 6, 8 and 10 is discovered, coexisting with a ferrimagnetic [0 0 0] phase at high Co-contents. The presence of electrical polarisation and spontaneous magnetisations offers possibilities for multiferroic properties.
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| http://dx.doi.org/10.1039/c8cc07556e | DOI Listing |
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