We explore the relaxation behavior of model colloidal gels under steady shear flow by means of orthogonal superposition rheometry. Fumed silica and carbon black dispersions in Newtonian matrices are used as a model system. As shear rate increases, the frequency dependent orthogonal moduli of the gels shift along the frequency axis without changing their shape, which finally can be superimposed to yield a single master curve. This indicates that the shear rate tunes a master clock for overall relaxation modes in the sheared colloidal gels to produce a "time-shear rate superposition (TSS)", as temperature does in polymeric liquids to produce a time-temperature superposition (TTS). The horizontal shift factor required at each shear rate to obtain the master curve is found to be directly proportional to the suspension viscosity for all the cases. From this result, we suggest that the suspension viscosity determines the overall relaxation time of the particles in the flowing colloidal gel.

Download full-text PDF

Source
http://dx.doi.org/10.1039/c8sm01512kDOI Listing

Publication Analysis

Top Keywords

colloidal gels
12
shear rate
12
orthogonal superposition
8
superposition rheometry
8
rate superposition
8
master curve
8
suspension viscosity
8
rate
5
colloidal
4
rheometry colloidal
4

Similar Publications

Blood clots (BCs) play a crucial biomechanical role in promoting osteogenesis and regulating mesenchymal stem cell (MSC) function and fate. This study shows that BC formation enhances MSC osteogenesis by activating Itgb1/Fak-mediated focal adhesion and subsequent Runx2-mediated bone regeneration. Notably, BC viscoelasticity regulates this effect by modulating Runx2 nuclear translocation.

View Article and Find Full Text PDF

Near-infrared wavelength-selective soft actuators have attracted much attention for applications in microsystems in bioliving. It is desirable for the photothermal conversion materials in the actuators to be downsized to the molecular scale. However, in conventional actuator materials using copolymer gels composed of thermosensitive and photothermal conversion molecule-coordinated monomers, the strong cross-linking of molecules in the networks impairs the actuator deformation.

View Article and Find Full Text PDF

Measuring XNA polymerase fidelity in a hydrogel particle format.

Nucleic Acids Res

January 2025

Department of Pharmaceutical Sciences, University of California, Irvine, CA 92697-3958, United States.

Growth in the development of engineered polymerases for synthetic biology has led to renewed interest in assays that can measure the fidelity of polymerases that are capable of synthesizing artificial genetic polymers (XNAs). Conventional approaches require purifying the XNA intermediate of a replication cycle (DNA → XNA → DNA) by denaturing polyacrylamide gel electrophoresis, which is a slow, costly, and inefficient process that requires a large-scale transcription reaction and careful extraction of the XNA strand from the gel slice. In an effort to streamline the assay, we developed a purification-free approach in which the XNA transcription and reverse transcription steps occur inside the matrix of a hydrogel-coated magnetic particle.

View Article and Find Full Text PDF

Gel immersion in endoscopy: Exploring potential applications.

World J Gastroenterol

January 2025

Department of Internal Medicine, Asahikawa Medical University, Asahikawa 078-8510, Hokkaido, Japan.

The challenge of effectively eliminating air during gastrointestinal endoscopy using ultrasound techniques is apparent. This difficulty arises from the intricacies of removing concealed air within the folds of the gastrointestinal tract, resulting in artifacts and compromised visualization. In addition, the overlap of folds with lesions can obscure their depth and size, presenting challenges for an accurate assessment.

View Article and Find Full Text PDF

Doxorubicin-induced cardiomyopathy (DOX-IC) is a significant and common complication in patients undergoing chemotherapy, leading to cardiac remodeling and reduced heart function. We hypothesized that the intrapericardial injection of hydrogels derived from the cardiac decellularized extracellular matrix (dECM) loaded with adipose tissue-derived stromal cells (ASC) and their secretome dampens or reverses the progression of DOX-IC. DOX-IC was induced in Wistar male rats through ten weekly intra-peritoneal injections of doxorubicin (cumulative dose: 18 mg/kg).

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!