Boron carbonyl complexes analogous to hydrocarbons.

Dalton Trans

Collaborative Innovation Center of Chemistry for Energy Materials, Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysts and Innovative Materials, Fudan University, Shanghai 200433, China.

Published: December 2018

Recent studies on boron carbonyl complexes show their intriguing structural and bonding properties, enriching our knowledge on main group coordination chemistry. The isolobal relationships between BCO and CH and the more generally applicable CO/H- and B-/C analogies are employed to understand the structure and bonding of boron carbonyl complexes, bridging the boron carbonyl chemistry to the well-known hydrocarbon analogues.

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Source
http://dx.doi.org/10.1039/c8dt03236jDOI Listing

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