The addition of oil to an extended surfactant-water system (sodium tetrapropylene glycol (2-ethyl)octyl ether sulfate, CPOSONa) induces the elongation of spherical micelles into oil-swollen branched wormlike micelles (WLMs) near the phase inversion point of the surfactant-oil-water (SOW) system. The hydrophilic-lipophilic-difference (HLD) framework, which has been associated with surfactant curvature, was successfully used to predict the conditions under which WLMs are produced for both polar and non-polar oils. At HLD = 0, the formation of low-curvature surfactant structures including WLMs and liquid crystals are favored in water-rich systems. Micellar growth begins around HLD = -0.5, and reaches a plateau upon the formation of a branched WLM network at HLD = 0. Above the entanglement concentration, the branched WLMs exhibit Maxwell and shear thinning behavior which is suitable for the suspension of nanoparticles, among others.
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http://dx.doi.org/10.1039/c8sm01673a | DOI Listing |
Cell Mol Biol (Noisy-le-grand)
January 2025
Department of Physiology, Faculty of Medicine, Tehran Medical Sciences, Islamic Azad University, Tehran, Iran.
Sci Rep
January 2025
Saint Petersburg State University, St. Petersburg, 198504, Russia.
Using angle-resolved photoemission spectroscopy (ARPES) and density functional theory (DFT), an experimental and theoretical study of changes in the electronic structure (dispersion dependencies) and corresponding modification of the energy band gap at the Dirac point (DP) for topological insulator (TI) [Formula: see text] have been carried out with gradual replacement of magnetic Mn atoms by non-magnetic Ge atoms when concentration of the latter was varied from 10% to 75%. It was shown that when Ge concentration increases, the bulk band gap decreases and reaches zero plateau in the concentration range of 45-60% while trivial surface states (TrSS) are present and exhibit an energy splitting of 100 and 70 meV in different types of measurements. It was also shown that TSS disappear from the measured band dispersions at a Ge concentration of about 40%.
View Article and Find Full Text PDFSci Rep
January 2025
A.V. Zhirmunsky National Scientific Center of Marine Biology, Far Eastern Branch, Russian Academy of Sciences, ul. Palchevskogo 17, Vladivostok, 690041, Russia.
J Biol Chem
January 2025
Developmental Therapeutics Branch, Center for Cancer Research, National Cancer Institute, Bethesda, MD, USA; Department of Oncology, Division of Oncology Research, Mayo Clinic, Rochester, MN, USA; Department of Molecular Pharmacology and Experimental Therapeutics, Mayo Clinic, Rochester, MN, USA. Electronic address:
The host-range mutant of rabbitpox virus (RPXV) with a deletion in the gene encoding the serpin serine protease inhibitor 1 (SPI-1) fails to replicate efficiently in restrictive host cells. Depletion of the host cell serine protease FAM111A restores viral replication in these cells, suggesting that SPI-1 targets FAM111A to facilitate infection. However, direct evidence of SPI-1 inhibiting FAM111A has been lacking.
View Article and Find Full Text PDFJ Hazard Mater
January 2025
College of Chemical and Environmental Engineering, Hanjiang Normal University, Shiyan 442000, China. Electronic address:
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