Fuel cells are a key new green technology that have applications in both transport and portable power generation. Carbon-supported platinum (Pt) is used as an anode and cathode electrocatalyst in low-temperature fuel cells fueled with hydrogen or low-molecular-weight alcohols. The cost of Pt and the limited world supply are significant barriers to the widespread use of these types of fuel cells. Comparatively, palladium has a 3 times higher abundance in the Earth's crust. Here, a facile, low-temperature, and scalable synthetic route toward three-dimensional nanostructured palladium (Pd) employing electrochemical templating from inverse lyotropic lipid phases is presented. The obtained single diamond morphology Pd nanostructures exhibited excellent catalytic activity and stability toward methanol, ethanol, and glycerol oxidation compared to commercial Pd black, and the nanostructure was verified by small-angle X-ray scattering, scanning tunneling electron microscopy, and cyclic voltammetry.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1021/acsami.8b13230 | DOI Listing |
Cell Commun Signal
January 2025
Department of Oncological Sciences, Icahn School of Medicine at Mount Sinai, One Gustave L. Levy Place, New York, NY, 10029, USA.
One hallmark of cancer is the upregulation and dependency on glucose metabolism to fuel macromolecule biosynthesis and rapid proliferation. Despite significant pre-clinical effort to exploit this pathway, additional mechanistic insights are necessary to prioritize the diversity of metabolic adaptations upon acute loss of glucose metabolism. Here, we investigated a potent small molecule inhibitor to Class I glucose transporters, KL-11743, using glycolytic leukemia cell lines and patient-based model systems.
View Article and Find Full Text PDFLett Appl Microbiol
January 2025
Amity Institute of Biotechnology, Amity University Rajasthan, Jaipur 303002, India.
Azo dyes constitute 60-70% of commercially used dyes and are complex, carcinogenic, and mutagenic pollutants that negatively impact soil composition, water bodies, flora, and fauna. Conventional azo dye degradation techniques have drawbacks such as high production and maintenance costs, use of hazardous chemicals, membrane clogging, and sludge generation. Constructed Wetland-Microbial Fuel Cells (CW-MFCs) offer a promising sustainable approach for the bio-electrodegradation of azo dyes from textile wastewater.
View Article and Find Full Text PDFAdv Colloid Interface Sci
January 2025
Breakthrough Technologies, Deakin, ACT, Australia.
The glycocalyx and its associated endothelial surface layer which lines all cell membranes and most tissues, dwarfs the phospholipid membrane of cells in extent. Its major components are sulphated polymers like heparan and chondroitin sulphates and hyaluronic acid. These form a fuzzy layer of unknown structure and function.
View Article and Find Full Text PDFMolecules
January 2025
Guangdong Provincial Key Laboratory of Fuel Cell Technology, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510641, China.
Solid polymer electrolytes (SPEs) have attracted much attention due to their excellent flexibility, strong interfacial adhesion, and good processibility. However, the poor interfacial contact between the separate solid polymer electrolytes and electrodes leads to large interfacial impedance and, thus, hinders Li transport. In this work, an ionic liquid-modified comb-like crosslinked network composite solid-state electrolyte with an integrated electrolyte/cathode structure is prepared by in situ ultraviolet (UV) photopolymerization.
View Article and Find Full Text PDFMolecules
January 2025
Orlen Unicre a.s., Revolucňí 1521/84, 400 01 Ústí nad Labem, Czech Republic.
The increasing global population and urbanization have led to significant challenges in waste management, particularly concerning vacuum blackwater (VBW), which is the wastewater generated from vacuum toilets. Traditional treatment methods, such as landfilling and composting, often fall short in terms of efficiency and sustainability. Anaerobic digestion (AD) has emerged as a promising alternative, offering benefits such as biogas production and digestate generation.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!