Bio-inspired consolidants derived from crystalline nanocellulose for decayed wood.

Carbohydr Polym

Department of Chemistry, Life Science and Environmental Sustainability, University of Parma, Parco Area delle Scienze 17/A, Parma, Italy.

Published: December 2018

Novel bio-inspired materials derived from crystalline nanocellulose (CNC) have been tested as wood consolidants. A suspension of CNC, produced by acid hydrolysis of cellulose and used as such or mixed with lignin and/or siloxane derivatives (PDMS), was applied on rotted wood samples of Norway spruce. X-Ray diffraction analysis on CNC powder showed high crystallinity index. Dynamic light scattering (DLS) measurement indicated a nearly uniform particle size distribution with an average hydrodynamic diameter for pure CNC smaller than that in the mixtures. Raman and FTIR spectroscopies suggested interactions between lignin, PDMS and CNC components. The storage modulus of wood samples, measured by Dynamic Mechanical Analysis on the same specimen before and after consolidation, confirmed the efficiency of pure CNC, which displayed a considerable improvement of stiffness. A substantial increase of E' was observed particularly for most decayed classes. These results suggest a closer interaction between nanocellulose and decayed wood.

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http://dx.doi.org/10.1016/j.carbpol.2018.08.132DOI Listing

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