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Arylation of benzyl amines with aromatic nitriles. | LitMetric
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Arylation of benzyl amines with aromatic nitriles.

Yingjie Lei Ju Yang Rupeng Qi Shan Wang Rui Wang Zhaoqing Xu

Chem Commun (Camb)

Key Laboratory of Preclinical Study for New Drugs of Gansu Province, The Institute of Pharmacology, School of Basic Medical Sciences, Lanzhou University, 199 West Donggang Road, Lanzhou 730000, China.

Published: October 2018

In the past years, the activations of aromatic nitriles for radical arylations under photoirradiation have been developed. We here report the first example of radical arylations using aromatic nitriles without the assistance of photoirradiation. Importantly, with this method, the direct arylation of C(sp)-H in benzyl amines provided a practical method for the synthesis of diarylmethylamines without the use of precious transition metal catalysts.

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http://dx.doi.org/10.1039/c8cc06408cDOI Listing

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