A millimetric liquid droplet may walk across the surface of a vibrating liquid bath through a resonant interaction with its self-generated wavefield. Such walking droplets, or "walkers," have attracted considerable recent interest because they exhibit certain features previously believed to be exclusive to the microscopic, quantum realm. In particular, the intricate motion of a walker confined to a closed geometry is known to give rise to a coherent wave-like statistical behavior similar to that of electrons confined to quantum corrals. Here, we examine experimentally the dynamics of a walker inside a circular corral. We first illustrate the emergence of a variety of stable dynamical states for relatively low vibrational accelerations, which lead to a double quantisation in angular momentum and orbital radius. We then characterise the system's transition to chaos for increasing vibrational acceleration and illustrate the resulting breakdown of the double quantisation. Finally, we discuss the similarities and differences between the dynamics and statistics of a walker inside a circular corral and that of a walker subject to a simple harmonic potential.
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Sci Total Environ
May 2024
Department of Chemistry, University of La Rioja, C/Madre de Dios 53, 26006 Logroño, La Rioja, Spain. Electronic address:
This research investigates the potential of utilizing vine shoots, a byproduct of the viticulture industry, as biosorbent for cadmium removal from aqueous solutions. The Spanish wine industry, one of the most influential sectors, produces two to three million tons of vine shoots. By using vine shoots as biosorbent, this study contributes to the circular economy paradigm, transforming waste materials into valuable resources and minimizing environmental impacts associated with waste generation and disposal.
View Article and Find Full Text PDFFront Chem
February 2023
Renal Division and Engineering in Medicine Division, Department of Medicine, Brigham and Women's Hospital, Harvard Medical School, Boston, MA, United States.
Lipid-bilayer nanodiscs and liposomes have been developed to stabilize membrane proteins in order to study their structures and functions. Nanodiscs are detergent-free, water-soluble, and size-controlled planar phospholipid-bilayer platforms. On the other hand, liposomes are curved phospholipid-bilayer spheres with an aqueous core used as drug delivery systems and model membrane platforms for studying cellular activities.
View Article and Find Full Text PDFJ Am Chem Soc
November 2022
College of Chemistry, Nankai University, 94 Weijin Road, Tianjin 300072, China.
Despite the advances in host-guest chemistry, macrocyclic hosts with deep cavities are far from abundant among the large number of wholly synthetic hosts described in the literature. Herein, we describe the design and synthesis of two new tubular hosts, namely, corral[4]arene and corral[5]arene. The former has been isolated and characterized as two conformational diastereoisomers, one is centrosymmetric and the other asymmetric.
View Article and Find Full Text PDFJ Phys Condens Matter
October 2022
Department of Mathematics, Western Kentucky University, Bowling Green, KY 42101, United States of America.
Two simple kinetic models of quantum size effect-directed nanocluster self-assembly in circular atomic corrals are discussed. The models correspond to an adsorption (either a physisorption or a chemisorption) and an adsorption-diffusion regimes that are typical at low and high temperatures, respectively. Small magnitudes of a variation of the electronic local density of states is shown to be the prime factor that impedes self-assembly in the latter regime.
View Article and Find Full Text PDFMembranes (Basel)
July 2022
Department of Engineering, Università di Palermo, 90128 Palermo, Italy.
Fouling is considered one of the main drawbacks of membrane bioreactor (MBR) technology. Among the main fouling agents, extracellular polymeric substances (EPS) are considered one of the most impactful since they cause the decrease of sludge filterability and decline of membrane flux in the long term. The present study investigated a biological strategy to reduce the membrane-fouling tendency in MBR systems.
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