Selective Coupling of Bioderived Aliphatic Alcohols with Acetone Using Hydrotalcite Derived Mg-Al Porous Metal Oxide and Raney Nickel.

Fermentation of sugars to the so-called ABE mixture delivers a three component mixture of shorter chain oxygenates: acetone, -butanol and ethanol. In order to convert these into liquid transportation fuels that are analogous to the currently used fossil energy carriers, novel catalytic chain elongation methods involving C-C bond formation are desired. Herein we report on a simple, non-noble-metal-based method for the highly selective coupling of 1-butanol and acetone into high molecular weight (C7-C11) ketones, as well as ABE mixtures into (C5-C11) ketones using the solid base Mg-Al-PMO in combination with small amount of Raney nickel. Upon hydrodeoxygenation, these ketones are converted to fuel range alkanes with excellent carbon utilization (up to 89%) using Earth abundant metal containing catalysis.