Even though additive manufacturing (AM) techniques have been available since the late 1980s, their application in medicine is still striving to gain full acceptance. For the production of dental implants, the use of AM allows to save time and costs, but also to ensure closer dimensional tolerances and higher repeatability, as compared to traditional manual processes. Among the several AM solutions, Laser Powder Bed Fusion (L-PBF) is the most appropriate for the production of metal prostheses. The target of this paper was to investigate the mechanical and microstructural characteristics of Co⁻Cr⁻Mo and Ti⁻6Al⁻4V alloys processed by L-PBF, with a specific focus on secondary anisotropy that is usually disregarded in the literature. Tensile specimens were built in the EOSINT-M270 machine, along different orientations perpendicular to the growth direction. Density, hardness, and tensile properties were measured and the results combined with microstructural and fractographic examination. For both alloys, the results provided evidence of high strength and hardness, combined with outstanding elongation and full densification. Extremely fine microstructures were observed, sufficient to account for the good mechanical response. Statistical analysis of the mechanical properties allowed to attest the substantial absence of secondary anisotropy. The result was corroborated by the observations of the microstructures and of the failure modes. Overall, the two alloys proved to be high-performing, in very close agreement with the values reported in the datasheets, independently of the build orientation.
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http://dx.doi.org/10.3390/ma11101831 | DOI Listing |
Angew Chem Int Ed Engl
January 2025
The University of Hong Kong, Department of Chemistry, Pokfulam Road, 999077, Hong Kong, CHINA.
Electrically conductive coordination polymers (ECCPs), particularly those incorporating benzenehexathiol (BHT) ligands, are emerging as a distinctive class of electronic materials with tunable semiconducting and metallic properties. However, the exploration of novel ECCPs with low-symmetry structures and electrical anisotropy remains under development. Here, we report the on-water surface synthesis of a novel ECCP, namely Cu5BHT, which exhibits a low-symmetry structure and unique in-plane electrical anisotropy that differs from the well-known Cu3BHT phase.
View Article and Find Full Text PDFJ Phys Chem B
January 2025
OncoImmunin, Inc., 207A Perry Parkway, Suite 6, Gaithersburg, Maryland 20877, United States.
We have previously found that the presence of an H-type excitonic dimer formed by two fluorophores covalently bound to an oligonucleotide allows the delivery of such a polymer into live cells without inducing toxicity. We are now using time-resolved fluorescence measurements in solution to understand the molecular dynamics of an antisense probe and how pairing with complementary sense strands of various lengths and degrees of complementarity affects the antisense strand's properties. We report that a DNA strand composed of 30 residues and labeled with an H-type excitonic Cyanine-5/Cyanine-5 dimer shows a predominant 1.
View Article and Find Full Text PDFMaterials (Basel)
December 2024
State Key Laboratory of Precision Welding & Joining of Materials and Structures, Harbin Institute of Technology, 92 West Dazhi Street, Harbin 15001, China.
This investigation focuses on Selective Laser Melting (SLM)-fabricated thin-walled Ta10W alloy components. Given the inherent limitations of SLM in producing large-scale, complex components in a single operation, laser welding was investigated as a viable secondary processing method for component integration. The study addresses the critical issue of weldability in additively manufactured tantalum-tungsten alloys, which frequently exhibit internal defects due to process imperfections.
View Article and Find Full Text PDFMaterials (Basel)
December 2024
Department of Chemistry, Lomonosov Moscow State University, Moscow 119991, Russia.
In this research paper, the factors impacting electrical conductivity of the flexible graphite foils (GFs) produced by different forming processes, namely, either by rolling or pressing, were studied. The relationship between electrical conductivity and texture and structure that formed when producing the material was examined. Correlation was determined between the texture sharpness and anisotropy of electrical conductivity, as well as the extent of impact from the substructural characteristics on the properties' values.
View Article and Find Full Text PDFBrain Inj
December 2024
Centre for Neuroscience Studies, Queen's University, Kingston, Ontario, Canada.
Objective: The purpose of this study was to determine whether gray matter volume and diffusion-based metrics in associated white matter changed in breachers who had neuroimaging performed at two timepoints. A secondary purpose was to compare these changes in a group who had a one-year interval between their imaging timepoints to a group that had a two-year interval between imaging.
Methods: Between timepoints, clusters with significantly different gray matter volume were used as seeds for reconstruction of associated structural networks using diffusion metrics.
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