Electrokinetic phenomena in a nematic suspension are considered when one or more dielectric particles are suspended in a liquid crystal matrix in its nematic phase. The long-range orientational order of the nematic constitutes a fluid with anisotropic properties. This anisotropy enables charge separation in the bulk under an applied electric field, and leads to streaming flows even when the applied field is oscillatory. In the cases considered, charge separation is seen to result from director field distortions in the matrix that are created by the suspended particles. We use a recently introduced electrokinetic model to study the motion of a single-particle hyperbolic hedgehog pair. We find this motion to be parallel to the defect-particle center axis, independent of field orientation. For a two-particle configuration, we find that the relative force of electrokinetic origin is attractive in the case of particles with perpendicular director anchoring, and repulsive for particles with tangential director anchoring. The study reveals large scale flow properties that are respectively derived from the topology of the configuration alone and from short scale hydrodynamics phenomena in the vicinity of the particle and defect.
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http://dx.doi.org/10.1103/PhysRevE.98.022703 | DOI Listing |
J Colloid Interface Sci
January 2025
International Research Center for Renewable Energy (IRCRE), State Key Laboratory of Multiphase Flow in Power Engineering (MFPE), Xi'an Jiaotong University (XJTU), Xi'an 710049 PR China.
Graphitic carbon nitride (g-CN) has been regarded as highly potential photocatalyst for solar energy utilization. However, the restricted absorption of visible light for pristine g-CN significantly limits the solar-light-driven chemical reaction efficiency. Herein, structurally distorted g-CN nanosheets with awakened n-π* electron transition were successfully synthesized through hexamethylenetetramine (HMTA)-involved supercritical CO (scCO) treatment and following pyrolysis of melamine precursor.
View Article and Find Full Text PDFJ Colloid Interface Sci
January 2025
College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China. Electronic address:
Rational regulation of interface structure in photocatalysts is a promising strategy to improve the photocatalytic performance of carbon dioxide (CO) reduction. However, it remains a challenge to modulate the interface structure of multi-component heterojunctions. Herein, a strategy integrating heterojunction with facet engineering is developed to modulate the interface structure of metal-organic frameworks (MOF)-based heterojunctions.
View Article and Find Full Text PDFJ Phys Chem Lett
January 2025
School of Chemistry, Indian Institute of Science Education and Research Thiruvananthapuram, Thiruvananthapuram, Kerala 695551, India.
Electronic coupling between individual redox units in a molecular assembly dictates their charge transfer efficacy. Being a well-defined crystalline structure, the metal-organic framework (MOF) ensures proper positioning of redox-active moieties and provides a unique platform to unveil their charge transfer dynamics and quantification with structural relationships. Here, we demonstrate a novel redox-active MOF with near-infrared through-space intervalence charge transfer by introducing a mixed valence state inside redox-active thiazolothiazole-based ligands (DPTTZ) upon photo- or electrochemical reduction.
View Article and Find Full Text PDFPolymers (Basel)
January 2025
School of Chemical Engineering, Yeungnam University, 280 Daehak-ro, Gyeongsan 38541, Republic of Korea.
Solid polymer electrolytes (SPEs) for symmetrical supercapacitors are proposed herein with activated carbon as electrodes and optimized solid polymer electrolyte membranes, which serve as the separators and electrolytes. We propose the design of a low-cost solid polymer electrolyte consisting of guanidinium nitrate (GuN) and poly(ethylene oxide) (PEO) with poly(vinylpyrrolidone) (PVP). Using the solution casting approach, blended polymer electrolytes with varying GuN weight percentage ratios of PVP and PEO are prepared.
View Article and Find Full Text PDFPolymers (Basel)
January 2025
Qatar Environment and Energy Research Institute, Hamad Bin Khalifa University, Qatar Foundation, Doha P.O. Box 34110, Qatar.
The development of ultrafiltration (UF) polymeric membranes with high flux and enhanced antifouling properties bridges a critical gap in the polymeric membrane fabrication research field. In the present work, the preparation of novel PES membranes incorporated with carrageenan (CAR), which is a natural polymer derived from edible red seaweed, is reported for the first time. The PES/CAR membranes were prepared by using the nonsolvent-induced phase separation (NIPS) method at 0.
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