The first La3+-selective metallohydrogel was constructed by using a facile gelator of a phenylalanine derivative containing an imidazole group, N-(1H-imidazol-4-yl)methylidene-l-phenylalanine, namely La-ImF, which exhibits multi-stimuli responsive properties, including to heat, shearing, pH, etc. Various measurements were also carried out to obtain insights into the mechanism of gelation. Moreover, the La-ImF hydrogel can adsorb toxic dyes, making it a potential candidate for sewage treatment.
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http://dx.doi.org/10.1039/c8dt03557a | DOI Listing |
Researchers have significantly focused on eco-friendly methods for nanomaterial synthesis to reduce the reliance on hazardous chemicals. In light of this, this study presents an eco-friendly, straightforward, alkali-free method for synthesizing iron-manganese (Fe-Mn) binary oxide (FMBO) and their single oxides by adopting a direct gel formation approach using starch. The synthesized materials were characterized through FTIR, FESEM, EDX, and XRD.
View Article and Find Full Text PDFBiomed Mater
November 2024
Materials Engineering Division, Lawrence Livermore National Laboratory, Livermore, CA, United States of America.
Thiol-norbornene photoclick hydrogels are highly efficient in tissue engineering applications due to their fast gelation, cytocompatibility, and tunability. In this work, we utilized the advantageous features of polyethylene glycol (PEG)-thiol-ene resins to enable fabrication of complex and heterogeneous tissue scaffolds using 3D bioprinting and in-air drop encapsulation techniques. We demonstrated that photoclickable PEG-thiol-ene resins could be tuned by varying the ratio of PEG-dithiol to PEG norbornene to generate a wide range of mechanical stiffness (0.
View Article and Find Full Text PDFCarbohydr Polym
January 2025
Decommissioning Technology Research Division, Korea Atomic Energy Research Institute, 989-111 Daedukdaero, Yuseong, Daejeon 34057, Republic of Korea.
For the first time, simple and facile fabrication of a magnetic alginate microadsorbent via piezoelectric inkjet technology was developed for the selective removal of Cs via magnetic separation. Through the ejection of an alginate solution containing potassium ferrocyanide and magnetic nanoparticles (MNPs) into a Cu solution via an inkjet device, the fabrication of a copper ferrocyanide-embedded magnetic alginate microadsorbent (CuFC-MAM) with an average size of 39.38 μm was easily achieved in a one-pot fabrication process; here, the Cu ions acted as both a cross-linker for the gelation of alginate and a Cu source for the in situ synthesis of CuFC with potassium ferrocyanide.
View Article and Find Full Text PDFChem Commun (Camb)
December 2024
Department of Chemical and Biomolecular Engineering, University of California, Los Angeles, Los Angeles, CA 90095, USA.
We report the synthesis of catechol-functionalized symmetric triblock polymers comprising densely functionalized catechol endblocks using anionic ring-opening polymerization (AROP) and thiol-ene click chemistry. The simplicity and modularity of our approach rely on a two-step synthesis that eliminates the need for catechol protection and enables the functionalization of precisely synthesized precursor polymers with catechol-containing thiols. Partial oxidation of the catechols on the triblock polymers to quinones enabled rapid gelation (within seconds) while retaining strong adhesive attributes.
View Article and Find Full Text PDFRepair and preservation of the injured meniscus has become paramount in clinical practice. However, the complexities of various clinic stitching techniques for meniscus repair pose challenges for grassroots doctors. Hence, there is a compelling interest in innovative therapeutic strategies such as bioadhesives.
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