Surface potassium dosing has been proven to be an effective method in tuning the electron doping and enhancing the superconducting transition temperatures in both iron chalcogenides and electron doped iron pnictides. However, it is not clear how surface potassium dosing affects the hole doping and superconductivity in hole doped Fe-based superconductors. Here we performed K-dosing on BaKFeAs, a prototypical hole-doped iron pnictide compound, and explored the electronic structure by in situ angle-resolved photoemission spectroscopy measurements. Starting from the slightly over-doped BaKFeAs, surface K-dosing effectively reduces the hole concentration towards optimal doping and enhances the superconductivity. Intriguingly, the enhancement of superconductivity does not slow down at optimal doping, and the gap further increases with K dosing even when the carrier doping effect is saturated. Meanwhile, the quasiparticle coherence of the inner hole pockets is enhanced by higher K dosing. Our results uncover a novel scattering-reduction effect of K-dosing in Ba K FeAs, which collaborates with the carrier doping effect and enhances superconductivity.
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http://dx.doi.org/10.1088/1361-648X/aae423 | DOI Listing |
Microorganisms
November 2024
State Key Laboratory of Food Nutrition and Safety, College of Food Science and Engineering, Tianjin University of Science and Technology, Tianjin 300457, China.
, an opportunistic foodborne pathogen, has a strong resistance to osmotic stress and desiccation stress, but the current studies cannot elucidate this resistance mechanism absolutely. A mechanosensitive channel MscM was suspected of involving to desiccation resistance mechanism of To investigate the specific molecular mechanism, the mutant strain (Δ) was constructed using the homologous recombination method, and the complementary strain was obtained by gene complementation, followed by the analysis of the difference between the wild-type (WT), mutant, and complementary strains. Compared to the wild-type bacteria (WT), the inactivation rate of the Δ strain decreased by 15.
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December 2024
Department of Mechatronics, Faculty of Technical Sciences, University of Warmia and Mazury in Olsztyn, 10-719 Olsztyn, Poland.
This study investigates the influence of prolonged electrolysis on the electrochemical performance and surface characteristics of NiFe-modified compressed graphite electrodes used in alkaline water electrolysis. The electrochemical experiment was conducted over a two-week period at a constant temperature of 60 °C. The electrodes were evaluated for changes in surface morphology and composition using scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), and X-ray diffraction (XRD).
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December 2024
Department of Physical Chemistry and Biophysics, Pharmaceutical Faculty, Wroclaw Medical University, Borowska 211, 50-556 Wroclaw, Poland.
The synthesis of poly(N-isopropyl acrylamide) (pNIPA)-based polymers via the surfactant-free precipitation polymerization (SFPP) method produced thermosensitive nanospheres with a range of distinctive physicochemical properties. Nano- and microparticles were generated using various initiators, significantly influencing particle characteristics, including the hydrodynamic diameter (D), which varied from 87.7 nm to 1618.
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December 2024
Instituto de la Grasa (IG), CSIC, Campus Universitario Pablo de Olavide, Edificio 46, Ctra. Utrera km 1, 41013 Sevilla, Spain.
Table olive processing implies losses of mineral nutrients and increased sodium levels due to using brine during fermentation and storage. This study investigated fortifying traditional table olives with mixtures of KCl, CaCl, and MgCl during packaging to enhance mineral content while reducing NaCl. This research analyses the distribution of cations between olives and brines and employed the Response Surface Methodology (RSM) to model mineral content and their contributions to the Reference Daily Intake (RDI).
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December 2024
KU Leuven, Department of Chemistry Celestijnenlaan 200F P.O. box 2404 B-3001 Leuven Belgium
Direct lithium extraction (DLE) from natural surface and geothermal brines is very challenging due to the low ratio of lithium to other metals, and the lack of suitable materials that bind lithium with sufficiently high selectivity. In this paper, a synergistic solvent extraction system is described that comprises a liquid ion exchanger (saponified bis(2-ethylhexyl)dithiophosphoric acid) and a lithium-selective ligand (2,9-dibutyl-1,10-phenanthroline) in an aliphatic diluent. The extraction mechanism was investigated and was confirmed to involve the binding of lithium to the selective ligand, while the liquid ion exchanger facilitates the transfer of metal ions from the aqueous to the organic phase.
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