Regio- and chemoselective rearrangement of terminal epoxides into methyl alkyl and aryl ketones.

Chem Commun (Camb)

Institut für Anorganische Chemie, Eberhard Karls Universität Tübingen, Auf der Morgenstelle 18, 72076 Tübingen, Germany.

Published: October 2018

The development of the highly active pincer-type rhodium catalyst 2 for the nucleophilic Meinwald rearrangement of functionalised terminal epoxides into methyl ketones under mild conditions is presented. An excellent regio- and chemoselectivity is obtained for the first time for aryl oxiranes.

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http://dx.doi.org/10.1039/c8cc06503aDOI Listing

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