Green method for efficient PdNPs deposition on carbon carrier in the microreactor system.

The synthesis of palladium nanoparticles and conditions of their deposition on active carbon fibers in the microreactor was described. All processes related with metal ion reduction, nucleation, and autocatalytic growth of particles as well as their deposition were carried out in the microreactor in only one cycle. Synthesis of palladium nanoparticles was carried out under different conditions, i.e., changing the initial concentration of metal ions and the reductant, at 40 °C. Depending on the conditions imposed, the nanoparticles of different size (hydrodynamic radius change from 12 to 37 nm) and shape (spherical, cube, pyramid) were obtained. It was also shown that flow conditions allow for much more efficient Pd deposition on active carbon fibers than the process carried out in the batch. It was observed that for concentrations of Pd(II) ions higher than 0.2 mM, the degree of fiber surface coverage increased significantly in comparison with the batch process.