Here, the performances of two different catalysts, Ce-ZnO and TiO2 synthetized in our laboratories, were compared with the commercial TiO2-P25 for degradation of a mixture of seven emerging pollutants under UV irradiation. The investigation included monitoring pollutants abatement in Milli-Q water and in wastewater effluent and identifying their transformation products by HPLC-HRMS. Structural characterization of intermediates supported by data available from literature allowed elucidation of the transformation pathways occurring in the presence of all investigated catalysts in the wastewater effluent. Preliminary results showed a good removal efficacy for almost all examined contaminants, even in real water matrix (i.e. wastewater effluent). The type of matrix and catalyst affects the number and/or the abundance of transformation products, which suggests differences in their transformation routes.
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http://dx.doi.org/10.1039/c8pp00311d | DOI Listing |
Nanomaterials (Basel)
December 2024
Faculty of Sciences, University of Novi Sad, 21000 Novi Sad, Serbia.
This review explores biochar's potential as a sustainable and cost-effective solution for remediating organic pollutants, particularly polycyclic aromatic hydrocarbons (PAHs) and pesticides, in water. Biochar, a carbon-rich material produced from biomass pyrolysis, has demonstrated adsorption efficiencies exceeding 90% under optimal conditions, depending on the feedstock type, pyrolysis temperature, and functionalization. High surface area (up to 1500 m/g), porosity, and modifiable surface functional groups make biochar effective in adsorbing a wide range of contaminants, including toxic metals, organic pollutants, and nutrients.
View Article and Find Full Text PDFJ Environ Manage
January 2025
School of Artificial Intelligence, Xidian University, No. 2 South Taibai Road, Xi'an, Shaanxi, 710071, China.
In the process of partial nitrification and anaerobic ammonia oxidation (anammox) for nitrogen removal, the process offers simple metabolic pathways, low operating costs, and high nitrogenous loading rates. However, since the partial nitrification-anammox (PN-anammox) process combines partial nitrification and anammox reactions within the same reactor, strict control of dissolved oxygen (DO) is essential. Additionally, assessing treatment performance through chemical measurement involves time lag, making it challenging to recover the biological process when issue arise, especially in the PN-anammox process, where strict DO control and the sensitivity of anammox bacteria to conditions and substrates demand timely intervention.
View Article and Find Full Text PDFJ Hazard Mater
December 2024
School of Environmental Science and Engineering, Southwest Jiaotong University, Chengdu, Sichuan 611756, China. Electronic address:
Although hydroxyl radicals (OH) degrade organic pollutants nonselectively, their mineralization rate during the treatment of waste leachate biological treatment effluent (BTL) using Fenton or Fenton-like systems is not high, and the reason is unknown. In this study, we investigated three typical Fenton-like systems that act on dissolved organic matter (DOM) in BTL. We analyzed the molecular composition of DOM resistant to OH, using ultrahigh resolution mass spectrometry.
View Article and Find Full Text PDFWater Res
January 2025
National Engineering Laboratory for Advanced Municipal Wastewater Treatment and Reuse Technology, Engineering Research Center of Beijing, Beijing University of Technology, Beijing 100124, PR China. Electronic address:
Hydroxylamine (HA) dosing is an effective strategy for promoting partial nitrification (PN); however, its impact on endogenous denitrification remains underexplored. In this study, long-term continuous HA dosing (1.4 mg/L) was introduced for over 110 days in a pilot-scale anaerobic/aerobic/anoxic (AOA) system treating municipal wastewater (66.
View Article and Find Full Text PDFPLoS One
January 2025
Grupo de Investigación Materiales con Impacto (Mat&mpac) Universidad de Medellín, Medellín, Colombia.
In this study, we utilized drinking water treatment sludge (WTS) to produce adsorbents through the drying and calcination process. These adsorbents were then evaluated for their ability to remove azithromycin (AZT) from aqueous solutions. The L-500 adsorbent, derived from the calcination (at 500°C) of WTS generated under conditions of low turbidity in the drinking water treatment plant, presented an increase in the specific surface area from 70.
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