For the first presented magnetic ordering-induced multiferroics with a metal-organic framework (MOF) of formula [CHNH][Co(HCOO)], we theoretically investigate its multiple ferroics. It is found that Dzyaloshinskii-Moriya interaction is a main cause that leads to non-zero magnetization, and electric polarization, and the induced electric polarization can be regulated by magnetic fields. As an assistant mechanism, magnon-magnon interaction and quantum fluctuation play an important role on ferroelectrics and magnetism. Our methods are based on the double-time Green's function and Holstein-Primakoff transformation. Theoretical results can be compared with experiments, though there are some discrepancies.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1088/1361-648X/aadc80 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Metal-organic frameworks (MOFs): A review of volatile organic compounds (VOCs) detection.
Talanta
December 2024
The First Dongguan Affiliated Hospital, Guangdong Medical University, Dongguan, 523700, China. Electronic address:
This research presents a systematic review of the application of metal-organic frameworks (MOFs) to detect volatile organic compounds (VOCs). VOCs, compounds with high vapor pressure at ambient temperature and normal pressure, are widely present in a variety of industrial and living environments. VOCs are not only hazardous to the environment but also have a severe impact on human health.
View Article and Find Full Text PDFExceptional CO and HS adsorption by tuning micro/mesopore ratios with embedded graphene oxide/N-doped carbon quantum dots in MIL-101(Cr): Experimental and computational insights.
J Colloid Interface Sci
December 2024
Nanotechnology Research Center, Research Institute of Petroleum Industry (RIPI), West Blvd. Azadi Sports Complex, P.O. Box 14665, 1998 Tehran, Iran.
Herein, a novel nanocomposite was developed to adjust the textural properties of metal-organic frameworks (MOFs) for adsorptive applications. To this end, nitrogen-doped carbon quantum dots/reduced graphene oxide nanocomposite (RC) was embedded into MIL-101(Cr) crystals, named RC-ML-x nanocomposites. The prepared nanoadsorbents were thoroughly characterized by different techniques.
View Article and Find Full Text PDFEntropy engineering activation of UiO-66 for boosting catalytic transfer hydrogenation.
Nat Commun
January 2025
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, 130012, Changchun, P. R. China.
High-entropy metal-organic frameworks (HE-MOFs) hold promise as versatile materials, yet current rare examples are confined to low-valence elements in the fourth period, constraining their design and optimization for diverse applications. Here, a novel high-entropy, defect-rich and small-sized (32 nm) UiO-66 (ZrHfCeSnTi HE-UiO-66) has been synthesized for the first time, leveraging increased configurational entropy to achieve high tolerance to doping with diverse metal ions. The lattice distortion of HE-UiO-66 induces high exposure of metal nodes to create coordination unsaturated metal sites with a concentration of 322.
View Article and Find Full Text PDFMetal Organic Framework Based on Photoactivated Aggregation-Induced Emission Molecule for Achieving Photoexcitation Regulation.
Chem Asian J
January 2025
University of Shanghai for Science and Technology, School of Materials and Chemistry, Shanghai, CHINA.
Ln-MOFs, composed of lanthanide ions and functional organic ligands, are porous materials with tunable structures and unique luminescent properties. However, the interplay between ligand AIE properties and the framework's "antenna effect" on MOF morphology is understudied. Here, Tb-D-Cam-TPTB was synthesized via solvothermal method using TPTB (persulfurated arene) as the primary ligand, D-Cam as the auxiliary ligand, and Tb3+ as the metal ion.
View Article and Find Full Text PDFStructures and properties of α-amylase and glucoamylase immobilized by ZIF-8 via one-pot preparation.
Enzyme Microb Technol
December 2024
Guangxi Key Laboratory of Natural Polymer Chemistry and Physics, College of Chemistry and Materials, Nanning Normal University, Nanning 530001, PR China.
The immobilization of α-amylase and glucoamylase using a metal-organic framework (enzyme@ZIF-8) was prepared in situ through a one-pot method. The morphology, crystal structure, and molecular characteristics of the free enzyme and enzyme@ZIF-8 were characterized. The enzyme@ZIF-8 exhibited the rhombic dodecahedron morphology, with a decrease in particle size.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!