Techno-economic analysis of geopolymer production from the coal fly ash with high iron oxide and calcium oxide contents.

J Hazard Mater

Department of Chemical & Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4, 117585, Singapore. Electronic address:

Published: January 2019

In this work, we firstly examined the technical feasibility of geopolymer synthesis from the coal fly ash with high iron oxide (48.84 wt.%) and calcium oxide (22.15 wt.%) contents. The heat resistance of geopolymer was represented by the dry weight loss which ranged from 2.5 to 4.9% and was better than that (11.7%) of OPC. However, the high iron oxide content made the acid resistance (13-14%) of geopolymer inferior to OPC. The economics of geopolymer production changes significantly upon the variation in the arrangement of material use and geopolymer price. The costs of NaSiO and NaOH and the benefit of geopolymer selling were the major factors affecting the economic feasibility of geopolymer production. When the NaSiO price was around 400 USD/ton, the geopolymer production will be profitable even if the geopolymer price was as low as 50 USD/ton. It is possible to improve the economics of geopolymer production by varying the arrangement of material use while not impairing the performance of geopolymer.

Download full-text PDF

Source
http://dx.doi.org/10.1016/j.jhazmat.2018.08.089DOI Listing

Publication Analysis

Top Keywords

geopolymer production
20
geopolymer
12
high iron
12
iron oxide
12
coal fly
8
fly ash
8
ash high
8
calcium oxide
8
feasibility geopolymer
8
economics geopolymer
8

Similar Publications

Heterogeneous dynamics in aging phosphate-based geopolymer.

J Chem Phys

January 2025

Institute of Theoretical and Applied Mechanics of the Czech Academy of Sciences, Centre Telč, 58856 Telč, Czech Republic.

The time-evolution of dynamics as well as microstructure and mechanical response of phosphate-based geopolymers was probed using x-ray photon correlation spectroscopy and rheological tests. The analyzed relaxation processes in the freshly prepared geopolymer mixes evidenced a q-independent mode of the autocorrelation function, ascribed to density fluctuations of the already established molecular network, undergoing reconfiguration without significant mass transport. Upon curing, the detected motions are localized and depict a system evolving toward structural arrest dominated by slower hyperdiffusive dynamics, characterized by a compressed exponential regime, pointing to a structural relaxation process subjected to internal stresses, in a context of marked dynamical and structural heterogeneity.

View Article and Find Full Text PDF

Geopolymer Foam with Low Thermal Conductivity Based on Industrial Waste.

Materials (Basel)

December 2024

Faculty of Materials Engineering and Physics, Cracow University of Technology, Jana Pawła II 37, 31-864 Cracow, Poland.

Geopolymer materials are increasingly being considered as an alternative to environmentally damaging concrete based on Portland cement. The presented work analyzed waste from mines and waste incineration plants as potential precursors for producing geopolymer materials that could be used to make lightweight foamed geopolymers for insulation applications. The chemical and phase composition, radioactivity properties, and leachability of selected precursors were analyzed.

View Article and Find Full Text PDF

Removal, conversion and utilization technologies of alkali components in bayer red mud.

J Environ Manage

January 2025

China MCC22 Group Corporation Ltd., No.16 Xingfu Road, Fengrun District, Tangshan, Hebei, China.

Bayer red mud is a highly alkaline industrial solid waste generated during alumina production, and its massive discharge and stockpiling poses significant environmental risks. The strong alkalinity of red mud is a primary challenge limiting its effective utilization. This study systematically analyzes the composition and characteristics of alkaline components in red mud, emphasizing the roles of soluble free alkali and chemically bound alkali in regulating its alkalinity.

View Article and Find Full Text PDF
Article Synopsis
  • The paper compares low-calcium fly ash-based geopolymer concrete with traditional OPC-based concrete in terms of performance, microstructure, and environmental effects.
  • Geopolymer concrete exhibited 11-16% greater strength, superior resistance to sulfate and acid attacks, but a slight strength reduction from increasing binder dosage beyond certain limits.
  • It is more environmentally friendly, requiring 25-33% less energy and producing 14-28% less CO2 emissions compared to OPC, although the use of alkaline activators in geopolymer production contributes to higher emissions in that specific area.
View Article and Find Full Text PDF

In light of the growing need to mitigate climate change impacts, this study presents an innovative methodology combining ensemble machine learning with experimental data to accurately predict the carbon dioxide footprint (CO-FP) of fly ash geopolymer concrete. The approach employs adaptive boosting to enhance decision tree regression (DTR) and support vector regression (SVR), resulting in a robust predictive framework. The models used key material features, including fly ash concentration, fine and coarse aggregates, superplasticizer, curing temperature, and alkali activator levels.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!