Choosing suitable substrate is key to improving the efficiency of wetland decontamination. However, little is known about the effect of particle size. In order to study the effect of substrate type and size on COD, TN, and TP removal from sewage, 1-2, 2-4, and 4-8 mm zeolite, 2-4, 4-8, and 8-16 mm gravel, and 2-4, 3-5, and 6-8 mm anthracite were selected for establishment of the constructed system of experimental media with three replications. Results showed that removal efficiency of COD, TN, and TP varied with different particle sizes of the same material. The greatest COD removal was achieved with 4-8 mm zeolite and gravel and 6-8 mm anthracite, with removal rates of 53.74%, 60.76%, and 62.93%, respectively. Denitrification is the main pattern of nitrogen removal in the artificial test column; results show that smaller particle size is more effective for removal of TN. The removal rate of TP is also higher with smaller sizes of gravel and anthracite, but the opposite pattern occurred with zeolite. The removal of COD, TP, and TN also varied by substrate type. Anthracite led to good removal of COD, TP, and TN. Zeolite was most effective for removal of TN but had lower removal of TP. Gravel has high removal rate for COD, and has a general removal effect on TP.
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http://dx.doi.org/10.13227/j.hjkx.201712009 | DOI Listing |
Langmuir
January 2025
Department of Chemical Engineering and Materials Research Institute, Pennsylvania State University, University Park, Pennsylvania 16802, United States.
The chemical reactivity of glass surfaces is often studied with elemental analysis techniques, and although such characterization methods provide insights on compositional changes from exposure to specific chemical conditions, molecule-specific chemical reactions are not determined unambiguously. This study demonstrates the use of reflection-absorption infrared spectroscopy (RAIRS) to detect molecular species on alkali-free boroaluminosilicate and alkali aluminosilicate glasses, using acetic acid vapor as a model reactant to probe reaction sites at the surface with or without pretreatment by aqueous solutions of varied pH. With the assistance of the theoretical calculation of spectral changes based on refractive indices of bulk materials, it was possible to identify the molecular species being removed and produced at the glass surface.
View Article and Find Full Text PDFImmunol Res
January 2025
, Auckland, New Zealand.
Cytotoxic DNAs, methylation, histones and histones binding proteins are speculated to induce DNA sensors. Under stressed condition, the antigenic patterns, PAMPs and DAMPs, trigger the hyperactive innate response through DNA, DNA-RNA hybrids, oligonucleotides, histones and mtDNA to initiate cGAMP-STING-IFN I cascade. HSV -1&2, HIV, Varicella- Zoster virus, Polyomavirus, Cytomegalovirus, and KSHV negatively regulate the STING-MAVS-TBK-1/1KKE pathway.
View Article and Find Full Text PDFTech Coloproctol
January 2025
Peritonectomy and Liver Cancer Unit, Department of Surgery, St George Hospital, Kogarah, NSW, Australia.
Background: The goal of cytoreductive surgery for peritoneal malignancy is to remove all macroscopic disease, which occasionally requires the excision of the umbilicus. While the absence of the umbilicus can be aesthetically undesirable for patients, umbilical reconstruction is rarely performed due to the perceived complexity and increased risk of wound infections (Sakata et al. in Colorectal Dis 23:1153-1157, 2021).
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
January 2025
School of Engineering, Deakin University, Waurn Ponds, Geelong, VIC, 3216, Australia.
Injecting CO into deep geological formations can be an effective carbon removal and storage technology to mitigate global climate change. Interaction of injected CO with rock formations changes pH and hydrochemistry within the deep injection zone (> 800 m depth). However, cap rocks and multiple tight aquitards typically act as barriers to protect the shallow aquifer from changes in the injection zone.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
January 2025
Department of Chemistry, Utkal University, Bhubaneswar, 751 004, Odisha, India.
This research highlights a sustainable approach for the design and synthesis of a magnetic nickel ferrite (NiFeO) catalyst reutilizing industrial waste, specifically iron ore tailing and Raney nickel catalyst processing waste, by simple co-precipitation method. Transforming waste materials into high-performance catalysts, this study aligns with the principles of a circular economy, addressing both environmental waste and pollution. Structural characterization by X-ray diffraction (XRD) and microscopic (FESEM and TEM) revealed the formation of well crystalline nano ferrite with NiFeO nanoparticles with cubic spinel structure.
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