Using a resonant structure, we have established large pressure gradients in a magnetized indium antimonide (InSb) plasma. This produces diamagnetic current in the milliampere range. The magnetic field generated by the current is sensed with a small magnetic coil. The operating frequency is about 230 kHz with a power level on the order of 100 mW. The InSb is magnetized with a 1 T magnetic field produced with permanent magnets. We show good agreement between our experimental measurements and the expected diamagnetic current.
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http://dx.doi.org/10.1063/1.5029356 | DOI Listing |
Chem Sci
October 2024
Institute for Materials Research, Tohoku University 2-1-1 Katahira Aoba-ku Sendai 980-8577 Japan
Molecule-based hybrid layered magnets provide an ideal platform for investigating the long-range spin-ordering process in low-dimensional magnetic systems. Within this context, a promising area of research is spin-sandwiched hybrid layered magnets. These materials offer the potential to explore how the spin, which is sandwiched between magnetic layers, is influenced by the internal magnetic fields generated by the magnetic layers.
View Article and Find Full Text PDFChem Asian J
January 2025
Department of Chemistry, Indian Institute of Technology Madras (IITM), Chennai, 600036, Tamil Nadu, India.
Classically, aromaticity portrays the unique stability and peculiar reactivities of cyclic planar conjugated systems with (4n+2) π electrons. Understanding the electronic environments in new chemical frameworks through experimental and theoretical validation is central to this ever-expanding theme in chemical science. Such investigations in curved π-surfaces have special significance as they can unravel the variations when the planarity requirement is slightly lifted.
View Article and Find Full Text PDFPhys Chem Chem Phys
October 2024
Research School of Chemistry and Applied Biomedical Sciences, National Research Tomsk Polytechnic University, Tomsk 634050, Russian Federation.
Magnetically induced ring-currents and magnetic susceptibilities have been calculated for the series of biphenylene sheets and biphenylene nanoribbons with armchair and zigzag edges with hydrogen atoms, as well as with bromine and fluorine atoms. Calculations have been performed at the density functional level of theory. It has been shown that biphenylene sheets and nanoribbons are characterized by dominant paratropic ring current, resulting in antiaromatic character.
View Article and Find Full Text PDFEntropy (Basel)
August 2024
Department of Natural Sciences, Institute of Electrophysics, Kálmán Kandó Faculty of Electrical Engineering, Óbuda University, Tavaszmezőu. 17, H-1084 Budapest, Hungary.
In a Wilberforce pendulum, two mechanical oscillators are coupled: one pertains to the longitudinal (tension) motion and the other to the rotational (twisting) motion. It is shown that the longitudinal magnetic moment of circular currents, and similarly the magnetic moment of a spin-chain, can exhibit a Wilberforce-like vibration. The longitudinal oscillation is related to the Langevin diamagnetism, while the twisting motion is superimposed on the magnetic moment and spin precession.
View Article and Find Full Text PDFPhys Chem Chem Phys
October 2024
School of Chemical Science and Engineering, Tongji University, Siping Road 1239, Shanghai 200092, P. R. China.
Metal compounds with = 1/2 coordination-frameworks have been emerging as new powerful qubit candidates. In this study, we have reported the CN-based coordination framework TMA[KCoFe(CN)] to be a qubit. We explored the magnetization dynamics and spin coherence of the magnetic dilution of the = 1/2 Fe(III) complex TMA[KFe(CN)] (TMA = tetramethylammonium) in its Co(III)-based diamagnetic analogue TMA[KCo(CN)].
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