Bench-Stable Nickel Precatalysts with Heck-type Activation.

Organometallics

Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States.

Published: August 2018

Herein, we report the synthesis and characterization of a new class of air- and moisture-stable phosphine-containing nickel(II) precatalysts, which activate through a Heck-type mechanism. The activities of the precatalysts are demonstrated with a carbonyl-ene coupling reaction.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6113681PMC
http://dx.doi.org/10.1021/acs.organomet.8b00351DOI Listing

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