White light-emitting diodes (LEDs) are becoming an alternative general light source, with huge energy savings compared to conventional lighting. However, white LEDs using phosphor(s) suffer from unavoidable Stokes energy converting losses, higher manufacturing cost, and reduced thermal stability. Here, we demonstrate electrically driven, phosphor-free, white LEDs based on three-dimensional gallium nitride structures with double concentric truncated hexagonal pyramids. The electroluminescence spectra are stable with varying current. The origin of the emission wavelength is studied by cathodoluminescence and high-angle annular dark field scanning transmission electron microscopy experiments. Spatial variation of the carrier injection efficiency is also investigated by a comparative analysis between spatially resolved photoluminescence and electroluminescence.
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http://dx.doi.org/10.1038/lsa.2016.30 | DOI Listing |
J Colloid Interface Sci
December 2024
College of Materials Science and Engineering, Qingdao University of Science and Technology, 53 Zhengzhou Road, Qingdao, Shandong 266042, China; Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, Shandong Key Laboratory of Biochemical Analysis, Qingdao University of Science and Technology, 53 Zhengzhou Road, Qingdao, Shandong 266042, China. Electronic address:
A universal theory for predicting the catalytic activity of hydrolytic nanozymes has yet to be developed. Herein, by investigating the polarization and hydrolysis mechanisms of nanomaterials towards amide bonds, carbocation charge was identified as a key electronic descriptor for predicting catalytic activity in amide hydrolysis. Through machine learning correlation analysis and the Sure Independence Screening and Sparsifying Operator (SISSO) algorithm, this descriptor was interpreted to associate with the d-band center and Lewis acidity on the nanomaterial surface.
View Article and Find Full Text PDFWater Res
December 2024
Department of Environmental and Resource Engineering, Technical University of Denmark, Bygningstorvet, Bygning 115, 2800 Kgs, Lyngby, Denmark. Electronic address:
Groundwater, essential for ecological stability and freshwater supply, faces escalating nitrate contamination. Traditional biological methods struggle with organic carbon scarcity and low temperatures, leading to an urgent need to explore efficient approaches for groundwater remediation. In this work, we proposed an inorganic bioelectric system designed to confront these challenges.
View Article and Find Full Text PDFPhys Rev Lett
December 2024
Departement de Physique Theorique, Universite de Geneve, 24 quai Ernest Ansermet, 1211 Geneve 4, Switzerland.
We consider resonant wavelike dark matter conversion into low-frequency radio waves in the Earth's ionosphere. Resonant conversion occurs when the dark matter mass and the plasma frequency coincide, defining a range m_{DM}∼10^{-9}-10^{-8} eV where this approach is best suited. Owing to the nonrelativistic nature of dark matter and the typical variational scale of the Earth's ionosphere, the standard linearized approach to computing dark matter conversion is not suitable.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
College of Material, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou 311121, P. R. China.
Thermoelectric technology enables the direct and reversible conversion of heat into electrical energy without air pollution. Herein, the stability, electronic structure, and thermoelectric properties of methoxy-functionalized MC(OMe) (M = Sc, Ti, V, Cr, Y, Zr, Nb, Mo, Hf, Ta, and W) were systematically investigated using first-principles calculations and semiclassical Boltzmann transport theory. All MXenes, except those with M = Cr, Mo, and W, can be synthesized by substituting Cl- and Br-functionalized MXenes with deprotonated methanol, with stability governed by the M-O bond strength.
View Article and Find Full Text PDFPhys Rev Lett
December 2024
Materials Science Division, Argonne National Laboratory, Lemont, Illinois 60439, USA.
Bilayers of two-dimensional van der Waals materials that lack an inversion center can show a novel form of ferroelectricity, where certain stacking arrangements of the two layers lead to an interlayer polarization. Under an external out-of-plane electric field, a relative sliding between the two layers can occur, accompanied by an interlayer charge transfer and a ferroelectric switching. We show that the domain walls that mediate ferroelectric switching are a locus of strong attractive interactions between electrons.
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