Raising the light absorption of the photoactive layer in polymer solar cells (PSCs) without increasing the layer thickness is desirable but challenging because of the low carrier mobility of organic materials. Herein, we used the coupled localized surface plasmon resonance of heterostructured Au-CuS nanocrystals (NCs) to improve the light-trapping capability of the photoactive layer of PSCs. Broadband light absorption and a considerable improvement of the power conversion efficiency were obtained when the photoactive layer was doped with a tiny amount of NCs. This can be explicated by the enhanced near-field intensity and broadband scattering properties of added NCs.
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http://dx.doi.org/10.1021/acsami.8b09101 | DOI Listing |
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January 2025
School of Advanced Materials Science and Engineering, Sungkyunkwan University, 2066, Seobu-ro, Jangan-gu, Suwon-si, Gyeonggi-do, 16419, Republic of Korea.
Solar hydrogen production using photoelectrochemical (PEC) cells requires the selection of cost-effective materials with high photoactivity and durability. CuBiO photocathodes possess an appropriate bandgap for efficient hydrogen production. However, their performance is limited by poor charge transport and interface voids formed due to the porous structure during annealing, which complicates the deposition of passivation overlayers.
View Article and Find Full Text PDFDalton Trans
January 2025
State Key Laboratory of Organic Electronics and Information Displays & Institute of Advanced Materials (IAM), School of Materials Science and Engineering, Nanjing University of Posts & Telecommunications, 9 Wenyuan Road, Nanjing 210023, China.
Formamidinium lead triiodide (FAPbI) has received significant attention in the field of perovskite solar cells (PSCs) owing to its excellent optoelectronic properties and high thermal stability. However, the photoactive α-FAPbI perovskites are highly susceptible to degradation into non-perovskite δ-FAPbI phases, especially under humid conditions, which severely diminishes the device performance of FAPbI PSCs. Here, we propose an interfacial seeding strategy for regulating crystallization and stabilizing α-FAPbI perovskites in humid air.
View Article and Find Full Text PDFMaterials (Basel)
January 2025
Departamento de Química Orgánica, Universidad de Zaragoza, 50009 Zaragoza, Spain.
Dye-sensitization is a promising strategy to improve the light absorption and photoactivity abilities of wide-bandgap semiconductors, like TiO. For effective water-splitting photoanodes with no sacrificial agents, the electrochemical potential of the dye must exceed the thermodynamic threshold needed for the oxygen evolution reaction. This study investigates two promising organic cyanoacrylic dyes, designed to meet that criterion by means of theoretical calculations.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Department of Chemistry, Sardar Patel University, Vallabh Vidyanagar 388120, Gujarat, India.
The development of devices capable of storing energy harnessed from photons is on the rise, owing to the increasing global energy demand for smart systems. The majority of reports in this field cover the use of integrated type devices, which houses a separate photovoltaic module and supercapacitor or battery. Herein, we are reporting a photocapacitor with a simple two-electrode design, capable of operating without a conventional electrolyte or metal ions.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing 314001, China.
The ground-state charge generation (GSCG) in photoactive layers determines whether the photogenerated carriers occupy the deep trap energy levels, which, in turn, affects the device performance of organic solar cells (OSCs). In this work, charge-quadrupole electrostatic interactions are modulated to achieve GSCG through a molecular strategy of introducing different numbers of F atom substitutions on the BTA3 side chain. The results show that 8F substitution (BTA3-8F) and 16F substitution (BTA3-16F) lead to different patterns of highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) energy level changes.
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