Severity: Warning
Message: file_get_contents(https://...@pubfacts.com&api_key=b8daa3ad693db53b1410957c26c9a51b4908&a=1): Failed to open stream: HTTP request failed! HTTP/1.1 429 Too Many Requests
Filename: helpers/my_audit_helper.php
Line Number: 176
Backtrace:
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 176
Function: file_get_contents
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 250
Function: simplexml_load_file_from_url
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 3122
Function: getPubMedXML
File: /var/www/html/application/controllers/Detail.php
Line: 575
Function: pubMedSearch_Global
File: /var/www/html/application/controllers/Detail.php
Line: 489
Function: pubMedGetRelatedKeyword
File: /var/www/html/index.php
Line: 316
Function: require_once
The wide application of fullerene C nanoparticles would inevitably lead to their release into the environment. In order to evaluate the environment risks of C and the subsequent effects on ecosystem health, a reliable quantitative methodology of C should be established. In this study, a rapid pretreatment method called low-density solvent-based dispersive liquid-liquid micro-extraction (DLLME) combined high-performance liquid chromatography-UV detector (HPLC-UV) was developed to detect C in environmental water. In this proposed method, toluene and methanol were chosen as the extraction solvent and the dispersive solvent, respectively. The optimized volume of extraction solvent and dispersive solvent were 100 μL and 10 μL, respectively. And the best shaking time was chosen as 10 min at room temperature for the optimal homogenization procedure for the extraction of C in water samples. The enrichment factor of 50 was obtained with 100 μL toluene, and the recoveries of C from various environmental samples were in the range of 81.4 ± 5.0-101.4 ± 6.2% at 1.25-5.00 µg/L spiked levels. The detection limits of C in tap water, surface water, living sewage and mining waste water were 0.19, 0.29, 0.34 and 0.22 μg/L, respectively. The low detection limit, good linear range and high recoveries of C in environmental water indicated that the proposed method could provide an efficient approach for the analysis and tracking of C in the environment.
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Source |
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http://dx.doi.org/10.1080/09593330.2018.1516804 | DOI Listing |
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