Thin film composite (TFC) membrane, which consists of polyamide (PA) active film rests on porous support layer, has been the major type of reverse osmosis (RO) membrane since its development by Cadotte in the 1970s, and has been remarkably used to produce clean water for human consumption and domestic utilization. In the past 30 years, different approaches have been exploited to produce the TFC membrane with high water flux, excellent salt rejection, and better chlorine/fouling resistance. In this brief review, we classify the techniques that have been utilized to improve the RO-TFC membrane properties into four categories: (1) Using alternative monomers to prepare the active layer; (2) modification of membrane surface; (3) optimization of polymerization reactions; and (4) incorporation of nanoparticles (NPs) into the membrane PA layer. This review can provide insights to guide future research and further propel the RO TFN membrane.
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http://dx.doi.org/10.3390/membranes8030068 | DOI Listing |
Heliyon
January 2025
MaREI Centre, University College Cork, Cork, Ireland.
Airborne wind energy is an emerging technology that can harness stronger and more consistent winds in higher altitudes using less mechanical and civil infrastructures than conventional wind energy systems. This article outlines a techno-economic study on using this technology for reverse osmosis seawater desalination in which a semi-permeable membrane process is used to remove salts and contaminants from water. To understand the techno-economic feasibility of such a system, this research work studies a 2 MW airborne wind-driven reverse osmosis plant.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Civil and Environmental Engineering Department, University of Houston, 4226 Martin Luther King Blvd, Houston, Texas 77204, United States.
The permeability-selectivity trade-off in polymeric desalination membranes limits the efficiency and increases the costs of reverse osmosis and nanofiltration systems. Ultrathin contorted polyamide films with enhanced free volume demonstrate an impressive 8-fold increase in water permeance while maintaining equivalent salt rejection compared to conventional polyamide membranes made with -phenylenediamine and trimesoyl chloride monomers. The solution-based molecular layer-by-layer (mLbL) deposition technique employed for membrane fabrication sequentially reacts a shape-persistent contorted diamine monomer with a trimesoyl chloride monomer, forming highly cross-linked, dense polyamide networks while avoiding the kinetic and mass transfer limitations of traditional interfacial polymerization.
View Article and Find Full Text PDFCommun Eng
January 2025
School of Computer Science and Engineering, Sun Yat-sen University, Guangzhou, China.
Large-scale optimal design problems involving nonlinear differential equations are widely applied in modeling such as craft manufacturing, chemical engineering and energy engineering. Herein we propose a fast and flexible holomorphic embedding-based method to solve nonlinear differential equations quickly, and further apply it to handle the industrial application of reverse osmosis desalination. Without solving nonlinear differential equations at each discrete point by a traditional small-step iteration approach, the proposed method determines the solution through an approximation function or approximant within segmented computational domain independently.
View Article and Find Full Text PDFRSC Adv
January 2025
Centre for Advanced Materials and Devices (CAMD), Department of Chemistry, Faculty of Science, University of Colombo Colombo Sri Lanka
The global scarcity of irrigation-grade water poses severe concerns in the agricultural sector. Desalination techniques including reverse osmosis, electrodialysis, capacitive deionization, membrane filtration, and multi-stage flash are some dynamic solutions to mitigate this challenge. In this study, novel bio-filter materials were explored and developed for the application of membrane-based electrodialysis.
View Article and Find Full Text PDFJ Phys Chem B
January 2025
Engineering Research Center of Membrane and Water Treatment of MOE, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, P. R. China.
Polyamide (PA) membranes are widely utilized in desalination and water treatment applications, yet the mechanisms underlying water transport within these amorphous polymer materials remain insufficiently understood. To gain more insight into these problems on a microscopic scale, we employ molecular dynamics (MD) simulations to analyze the relationship between the structural properties and the water permeation behavior of PA membranes. Two distinct atomistic models of PA membranes are developed by controlling their degrees of cross-linking (DC).
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