High-efficiency large-area perovskite photovoltaic modules achieved via electrochemically assembled metal-filamentary nanoelectrodes.

Realizing industrial-scale, large-area photovoltaic modules without any considerable performance losses compared with the performance of laboratory-scale, small-area perovskite solar cells (PSCs) has been a challenge for practical applications of PSCs. Highly sophisticated patterning processes for achieving series connections, typically fabricated using printing or laser-scribing techniques, cause unexpected efficiency drops and require complicated manufacturing processes. We successfully fabricated high-efficiency, large-area PSC modules using a new electrochemical patterning process. The intrinsic ion-conducting features of perovskites enabled us to create metal-filamentary nanoelectrodes to facilitate the monolithic serial interconnections of PSC modules. By fabricating planar-type PSC modules through low-temperature annealing and all-solution processing, we demonstrated a notably high module efficiency of 14.0% for a total area of 9.06 cm with a high geometric fill factor of 94.1%.