Employing large-scale quantum Monte Carlo simulations, we study the extended XXZ model on the kagome lattice. A Z_{2} quantum spin liquid phase with effective even Ising gauge field structure emerges from the delicate balance among three symmetry-breaking phases including stripe solid, staggered solid, and ferromagnet. This Z_{2} spin liquid is stabilized by an extended interaction related to the Rokhsar-Kivelson potential in the quantum dimer model limit. The phase transitions from the staggered solid to a spin liquid or ferromagnet are found to be first order and so is the transition between the stripe solid and ferromagnet. However, the transition between a spin liquid and ferromagnet is found to be continuous and belongs to the 3D XY^{*} universality class associated with the condensation of spinons. The transition between a spin liquid and stripe solid appears to be continuous and associated with the condensation of visons.
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http://dx.doi.org/10.1103/PhysRevLett.121.057202 | DOI Listing |
Environ Res
January 2025
School of Environment and Energy Engineering, Anhui Jianzhu University, Hefei, 230601, China.
The efficient degradation of SAs is a significant challenge for the treatment of wastewater. To address this, the FeS@BC was prepared by calcining a mixture of pyrite and biomass, and used to activate peroxydisulfate (PDS) to degrade sulfadiazine (SDZ). The effect of carbon sources (wheat straw, rice husk, and corn cob) on catalytic activity of FeS@BC were investigated by Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), total Fe dissolution and free radical quantification.
View Article and Find Full Text PDFLangmuir
January 2025
School of Environment and Architecture, University of Shanghai for Science and Technology, Shanghai 200093, China.
Herein, first, MIL-125 samples were synthesized via a hydrothermal method. Then, Ag species were doping on the surface of MIL-125 samples via the photolysis of silver nitrate. Finally, the Z-scheme MIL-125/Ag/BiOBr composite was synthesized via a directed liquid assembly method.
View Article and Find Full Text PDFActa Crystallogr B Struct Sci Cryst Eng Mater
February 2025
Neutron Scattering Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA.
The search for a Kitaev quantum spin liquid in crystalline magnetic materials has fueled intense interest in the two-dimensional honeycomb systems. Many promising candidate Kitaev systems are characterized by a long-range-ordered magnetic structure with an antiferromagnetic zigzag-type order, where the static moments form alternating ferromagnetic chains. Recent experiments on high-quality single crystals uncovered the existence of intriguing multi-k magnetic structures, which evolved from zigzag structures.
View Article and Find Full Text PDFJ Phys Chem B
January 2025
Department of Physical Chemistry, Sciences II, University of Geneva, 30 Quai Ernest Ansermet, Geneva 1211, Switzerland.
The formation of protein condensates (droplets) via liquid-liquid phase separation (LLPS) is a commonly observed phenomenon in vitro. Changing the environmental properties with cosolutes, molecular crowders, protein partners, temperature, pressure, etc. has been shown to favor or disfavor the formation of protein droplets by fine-tuning the water-water, water-protein, and protein-protein interactions.
View Article and Find Full Text PDFChemistry
January 2025
Indian Institute of Science Education and Research (IISER), Chemistry, Dr. Homi Bhabha Road, Pashan, 411008, Pune, INDIA.
Metal-organic frameworks (MOFs) are a fascinating class of structured materials with diverse functionality originating from the distinctive physicochemical properties. This review focuses on the specific chemical design of geometrically frustrated MOFs along with the origin of the intriguing magnetic properties. We have discussed the arrangement of spin centres (metal and ligand) which are responsible for the unusual magnetic phenomena in MOFs.
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