As the characteristic scale of products and production processes decreases, the plasticity phenomena observed start to deviate from those evidenced at the macroscale. The current research aims at investigating this gap using a lower-order gradient enhanced approach both using phenomenological continuum level as well as crystal plasticity models. In the phenomenological approach, a physically based hardening model relates the flow stress to the density of dislocations where it is assumed that the sources of immobile dislocations are both statistically stored (SSDs) as well as geometrically necessary dislocations (GNDs). In the crystal plasticity model, the evolution of the critical resolved shear stress is also defined based on the total number of dislocations. The GNDs are similarly incorporated in the hardening based on projecting the plastic strain gradients through the Burgers tensor on slip systems. A rate-independent formulation is considered that eliminates any artificial inhomogeneous hardening behavior due to numerical stabilization. The behavior of both models is compared in simulations focusing on the effect of structurally imposed gradients versus the inherent gradients arising in crystal plasticity simulations.
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http://dx.doi.org/10.3390/ma11081425 | DOI Listing |
Tissue Eng Regen Med
January 2025
Department of Plastic Surgery, Hand Surgery-Burn Center, University Hospital RWTH Aachen, Pauwelsstraße 30, 52074, Aachen, Germany.
Background: Because of its biocompatibility and its soft and dynamic nature, the grafting of adipose tissue is regarded an ideal technique for soft-tissue repair. The adipose stem cells (ASCs) contribute significantly to the regenerative potential of adipose tissue, because they can differentiate into adipocytes and release growth factors for tissue repair and neovascularization to facilitate tissue survival. The present study tested the effect of administering a chronic low dose of ∆-tetrahydrocannabinol (THC) on these regenerative properties, in vitro and in vivo.
View Article and Find Full Text PDFInorg Chem
January 2025
College of Chemistry and Materials Science, College of Environmental and Resource Sciences, Fujian Provincial Key Laboratory of Advanced Materials Oriented Chemical Engineering, Fujian Normal University, Fuzhou 350007, China.
The glassy state of inorganic-organic hybrid metal halides combines their excellent optoelectronic properties with the outstanding processability of glass, showcasing unique application potential in solar devices, display technologies, and plastic electronics. Herein, by tailoring the organic cation from -phenylpiperazine to dimethylamine gradually, four types of zero-dimensional antimony halides are obtained with various optical and thermal properties. The guest water molecules in crystal (-phenylpiperazine)SbCl·Cl·5HO lead to the largest distortion of the Sb-halogen unit, resulting in the red emission different from the yellow emission of other compounds.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
Department of Food Science, Federal University of Lavras (UFLA), Lavras 37200-000, Brazil.
The use of active packaging made from biodegradable polymers can contribute to the environment and to the food industry by increasing the shelf life of their products. This study aimed to produce chitosan-based films incorporated with the invertase enzyme (1, 2, 5, 9, and 10 %) as an alternative to avoid sucrose crystallization in the confectionery industry. The optimum activity of the invertase enzyme was observed at 55 °C and pH 5, thus, the films made with the film-forming solution adjusted to pH 5 and dried at 55 °C were compared with those without pH adjustment and dried at room temperature.
View Article and Find Full Text PDFSmall
January 2025
Key Laboratory of Eco-chemical Engineering, International S&T Cooperation Foundation of Eco-chemical Engineering and Green Manufacture, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, 266042, P. R. China.
Crafting anisotropically epitaxial p-n heterostructures with Z-scheme charge transmission is a promising avenue toward excellent photocatalytic efficiency, yet the large lattice mismatch and diverse crystal growth habits between components have often arisen as a big challenge to this goal. Here, anisotropically epitaxial p-n heterostructures with 19.8% lattice mismatch are obtained via a dynamics-mediated seeded growth tactic under reaction temperature as low as 60 °C.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
December 2024
School of Materials Science and Engineering, State Key Laboratory of Fine Chemicals, Frontiers Science Center for Smart Materials Oriented Chemical Engineering, Technology Innovation Center of High Performance Resin Materials (Liaoning Province), Dalian University of Technology, Dalian, 116024, China.
Sodium-metal batteries (SMBs) using solid-state polymer electrolytes (SPEs) show impressive superiority in energy density and safety. As promising candidates for SPEs, solid-state plastic crystal electrolytes (SPCE) based on succinonitrile (SN) plastic crystal could achieve high ion conductivity and wide voltage window. Nonetheless, the notorious SN decomposition reaction on the electrode/electrolyte interface seriously challenges the stable operation of the battery.
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