Facile synthesis of hierarchical CNF/SnO/Ni nanostructures via self-assembly process as anode materials for lithium ion batteries.

R Soc Open Sci

State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun, 130012, People's Republic of China.

Published: June 2018

Hierarchical carbon nanofibre (CNF)/SnO/Ni nanostructures of graphitized carbon nanofibres and SnO nanocrystallines and Ni nanocrystallines have been prepared via divalent tin-alginate assembly on polyacrylonitrile (PAN) fibres, controlled pyrolysis and ball milling. Fabrication is implemented in three steps: (1) formation of a tin-alginate layer on PAN fibres by coating sodium alginate on PAN in a water medium followed by polycondensation in SnCl solution; (2) heat treatment at 450°C in a nitrogen atmosphere; (3) ball milling the mixture of CNF/SnO fibres and Ni powder. The CNF/SnO/Ni nanocomposite exhibits good lithium ion storage capacity and cyclability, providing a facile and low-cost approach for the large-scale preparation of anode materials for lithium ion batteries.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6030287PMC
http://dx.doi.org/10.1098/rsos.171522DOI Listing

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