Ideally, pressure driven membrane processes used in wastewater treatment such as reverse osmosis and nanofiltration should provide a complete physical barrier to the passage of pathogens such as enteric viruses. In reality, manufacturing imperfections combined with membrane ageing and damage can result in breaches as small as 20 to 30 nm in diameter, sufficient to allow enteric viruses to contaminate the treated water and compromise public health. In addition to continuous monitoring, frequent demonstration of the integrity of membranes is required to provide assurance that the barrier to the passage of such contaminants is intact. Existing membrane integrity monitoring systems, however, are limited and health regulators typically credit high-pressure membrane systems with only 2 log virus rejection, well below their capability. A reliable real-time method that can recognize the true rejection potential of membrane systems greater than 4 log has not yet been established. This review provides a critical evaluation of the current methods of integrity monitoring and identifies novel approaches that have the potential to provide accurate, representative virus removal efficiency estimates.
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http://dx.doi.org/10.3390/membranes8030060 | DOI Listing |
ACS Nano
January 2025
Center for High Pressure Science (CHiPS), State Key Laboratory of Metastable Materials Science & Technology, Yanshan University, Qinhuangdao 066004, China.
Moiré superlattices, created by stacking different van der Waals materials at twist angles, have emerged as a versatile platform for exploring intriguing phenomena such as topological properties, superconductivity, the quantum anomalous Hall effect, and the unconventional Stark effect. Additionally, the formation of moiré superlattice potential can generate spontaneous symmetry breaking, leading to an anisotropic optical response and electronic transport behavior. Herein, we propose a two-step chemical vapor deposition (CVD) strategy for synthesizing WS/SbS moiré superlattices.
View Article and Find Full Text PDFJ Sep Sci
December 2024
Departamento de Química, Universidade Federal de Santa Catarina, Florianopolis, Brazil.
This study introduces a green approach to sample preparation by applying natural deep eutectic solvents (NADES) to determine phthalates in carbonated soft drinks using high-performance liquid chromatography with diode array detector (HPLC-DAD). The method employs hollow fiber-microporous membrane liquid-liquid microextraction combined with a 96-well plate system, utilizing fatty-acid-based DES in the pores of the membranes. This methodology substantially reduces the use of organic solvents, and its efficiency is comparable to or better than conventional methods.
View Article and Find Full Text PDFRes Sq
December 2024
Department of Biochemistry, Vanderbilt University School of Medicine, Nashville, TN, 37232, USA.
Cytochromes P450 (CYP) form one of the largest enzyme superfamilies on Earth, with similar structural fold but biological functions varying from synthesis of physiologically essential compounds to metabolism of myriad xenobiotics. Here we determined the crystal structures of and human sterol 14α-demethylases (CYP51s). Both structures reveal elements that imply elevated conformational flexibility, uncovering molecular basis for faster catalytic rates, lower substrate selectivity, and resistance to inhibition.
View Article and Find Full Text PDFACS ES T Water
December 2024
Faculty of Applied Natural Sciences, Technische Hochschule Köln, 51379 Leverkusen, Germany.
Electroplating is a widely used technology for anticorrosion materials and decorative coatings. In view of the transition to a circular economy, the current electroplating wastewater treatment disposing of heavy metal sludge and wastewater severely lacks sustainability. Authors recently reported the successful recycling of electroplating agents using hybrid semibatch/batch reverse osmosis technology (hybrid RO).
View Article and Find Full Text PDFInt J Mol Sci
December 2024
Department of Food Microbiology, Meat Technology and Chemistry, Faculty of Food Science, University of Warmia and Mazury, Plac Cieszyński 1, 10-726 Olsztyn, Poland.
The study aimed to assess the high-pressure processing (HPP) impact on antibiotic resistance gene transfer in from food and food processing environments, both in vitro (in microbiological medium) and in situ (in carrot juice), using the membrane filter method. Survival, recovery, and frequency of antibiotic resistance gene transfer analyses were performed by treating samples with HPP at different pressures (200 MPa and 400 MPa). The results showed that the higher pressure (400 MPa) had a significant effect on increasing the transfer frequency of genes such as , encoding fosfomycin resistance, and , , , responsible for tetracycline resistance, both in vitro and in situ.
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