Catalytic enantioselective conjunctive cross-coupling has been developed to construct tertiary alkylboronic esters. These reactions occur with good yield and enantioselectivity for a range of substrates. Mechanistic experiments reveal aspects of the catalytic cycle that allow hindered substrates to react without significant complicating side reactions.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6414220 | PMC |
| http://dx.doi.org/10.1002/anie.201807775 | DOI Listing |
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