In this study, a novel air-assisted liquid-liquid microextraction (AALLME) method was developed for the HPLC determination of bisphenols migration from disposable plastic lunch box to contacting water. The AALLME was carried out in commercially-available medical plastic syringes with low-density extraction solvent (n-octanol), and the reaction of NaHCO and HCl was introduced to simultaneously induce the in-situ phase separation and salt effect. After the AALLME processes, the upper organic phase was pushed into the end of syringes (narrow tube) by moving the piston so that it could be readily collected for the HPLC analysis. The factors including the type and volume of extraction solvent, NaHCO addition and extraction cycles were optimized. Under the optimal conditions, the limits of detection (LODs) for target bisphenols were evaluated to be 0.2-0.7 μg L, and good linearities with correlation coefficients higher than 0.9955 were obtained. The recoveries for target bisphenols ranged from 80% to 106%, with the relative standard deviations (RSDs) of 4.4-14.1%. The proposed method was successfully applied to investigate the migration of bisphenols from the disposable plastic lunch boxes to the contacting water, revealing that compared to the conventional water-bath heating, the microwave heating could induce the significant migration of bisphenols in a much shorter time.
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http://dx.doi.org/10.1016/j.talanta.2018.06.072 | DOI Listing |
Adv Mater
December 2024
Department of Mechanical Science and Engineering, The Grainger College of Engineering, University of Illinois Urbana-Champaign, Urbana, IL, 61801, USA.
To tackle the formidable challenges posed by extreme cold weather events, significant advancements have been made in developing functional surfaces capable of efficiently removing accreted ice. Nevertheless, many of these surfaces still require external energy input, such as electrical power, which raises concerns regarding their alignment with global sustainability goals. Over the past decade, increasing attention has been directed toward photothermal surface designs that harness solar energy-a resource available on Earth in quantities exceeding the total reserves of coal and oil combined.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
December 2024
Department of Environmental Sciences and Technology, Central University of Punjab, Bathinda, 151001, Punjab, India.
In this study, water extract from Indian rosewood tree leaves was used to synthesize copper oxide nanoparticles (CuO NPs), further loaded on graphene oxide sheets to synthesize a novel nanocomposite (CuO@GO@IR). The maximum tetracycline removal was achieved at optimum conditions of pH 3, adsorbent dose 0.03g/50 mL, and 240 min contact time.
View Article and Find Full Text PDFChem Pharm Bull (Tokyo)
December 2024
Department of Pharmaceutical Engineering, School of Pharmacy, Aichi Gakuin University.
A co-amorphous state composed of probucol (PC) and fluvastatin sodium salt (FLU) was prepared by spray-drying (SD). We have previously reported that PC and atorvastatin calcium trihydrate salt (ATO) formed a co-amorphous state when prepared by a SD method and that the solubility of PC and the amorphous stability were improved by the preparation of the co-amorphous state. In the present study, the physicochemical properties, including the amorphous stability of the prepared co-amorphous state, were characterized.
View Article and Find Full Text PDFJ Mol Graph Model
December 2024
CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pune 411008, India; Academy of Scientific and Innovative Research (AcSIR), Ghaziabad, 201 002, India. Electronic address:
Multi-scale models in which varying resolutions are considered in a single molecular dynamics simulation setup are gaining importance in integrative modeling. However, combining atomistic and coarse-grain resolutions, especially for coarse-grain force fields derived from top-down approaches, have not been well explored. In this study, we have implemented and tested a dual-resolution simulation approach to model globular proteins in atomistic detail (represented by the CHARMM36 model) with the surrounding solvent in Martini2 coarse-grain detail.
View Article and Find Full Text PDFJ Colloid Interface Sci
December 2024
Key Laboratory of Eco-chemical Engineering, Ministry of Education, International Science and Technology Cooperation Base of Eco-chemical Engineering and Green Manufacturing, College of Chemistry and Molecular Engineering, Qingdao University of Science & Technology, 53 Zhengzhou Road, 266042 Qingdao, PR China. Electronic address:
The development of suitable support to maximize the atomic utilization efficiency of platinum is of great significance for the hydrogen evolution reaction (HER). Herein, we report a simple and fast nonequilibrium-corrosive approach to prepare oxygen defect-enriched FeO decorated with trace Pt onto nickel-iron foam (Pt/FeO-O/NIF). The Pt/FeO-O/NIF electrode is superhydrophilic with intimate contact with the electrolyte.
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