We use spin-polarized scanning tunneling microscopy to demonstrate that Ho atoms on magnesium oxide exhibit a coercive field of more than 8 T and magnetic bistability for many minutes, both at 35 K. The first spontaneous magnetization reversal events are recorded at 45 K, for which the metastable state relaxes in an external field of 8 T. The transverse magnetic anisotropy energy is estimated from magnetic field and bias voltage dependent switching rates at 4.3 K. Our measurements constrain the possible ground state of Ho single-atom magnets to either J_{z}=7 or 8, both compatible with magnetic bistability at fields larger than 10 mT.
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http://dx.doi.org/10.1103/PhysRevLett.121.027201 | DOI Listing |
ChemSusChem
January 2025
Beijing Jiaotong University, School of Science, School of Science, Beijing Jiaotong University, Beijing, 100044, P. R. China, 100044, Beijing, CHINA.
The eco-friendly features and desirable catalytic activities of Fe-based catalysts make them highly promising for propane dehydrogenation (PDH). However, simultaneously improving their stability and activity remains a challenge. Here, we present a strategy to address these issues synergistically by anchoring single-atom Fe-Cl sites in Al3+ vacancies of Al2O3.
View Article and Find Full Text PDFNat Commun
January 2025
National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, 230029, China.
The precise fabrication and regulation of the stable catalysts with desired performance still challengeable for single atom catalysts. Here, the Ru single atoms with different coordination environment in NiFeN lattice are synthesized and studied as a typical case over alkaline methanol electrooxidation. The NiFeN with buried Ru atoms in subsurface lattice (NiFeN-Ru) exhibits high selectivity and Faradaic efficiency of methanol to formate conversion.
View Article and Find Full Text PDFAdv Sci (Weinh)
January 2025
Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials, Ministry of Education, Shandong University, Jinan, 250061, China.
The absence of the enhancement of fluorescence in carbon dots (CDs) through doping with transition metal atoms (TMAs) hinders the advancement of multi-modal bio-imaging CDs with high photoluminescence quantum yield (PLQY). Herein, Mn-atomically-doped R-CDs (R-Mn-CDs) with a high PLQY of 41.3% in water is presented, enabling efficient in vivo dual-mode fluorescence/magnetic resonance (MR) imaging.
View Article and Find Full Text PDFAdv Mater
December 2024
Shaanxi Key Laboratory of Macromolecular Science and Technology, School of Chemistry and Chemical Engineering, Northwestern Polytechnical University, Xi'an, Shaanxi, 710072, P. R. China.
By manipulating their asymmetric electronic spin states, the unique electronic structures and unsaturated coordination environments of single atoms can be effectively harnessed to control their magnetic properties. In this research, the first investigation is presented into the regulation of magnetic properties through the electronic spin states of single atoms. Magnetic single-atom one-dimensional materials, M-N-C/ZrO (M = Fe, Co, Ni), with varying electronic spin states, are design and synthesize based on the electronic orbital structure model.
View Article and Find Full Text PDFPhys Chem Chem Phys
December 2024
School of Physics, Henan Normal University, Xinxiang, Henan, 453007, China.
Electrochemical reduction of naturally abundant nitrogen (N) under ambient conditions is a promising method for ammonia (NH) synthesis, while the development of a highly active, stable and low-cost catalyst remains a challenge. Herein, the N reduction reaction of TM@g-BCN in electrochemical nitrogen reduction has been systematically investigated using density functional theory (DFT) calculations and compared with that of TM@g-CN. It was found that TM atoms are more stably anchored to g-BCN than to g-CN.
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