A metal-free PhI(OAc)-mediated method for the synthesis of acyl azides through oxidative cleavage of 1,3-diketones is described. This method is shown to have a broad substrate scope, providing a useful tool for multiproduct synthesis in a single procedure. A possible reaction pathway is proposed based on mechanistic studies.
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| http://dx.doi.org/10.1021/acs.joc.8b01417 | DOI Listing |
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