The controlled transformation of materials, both their structure and their physical properties, is key to many devices. Ionic liquid gating can induce the transformation of thin-film materials over long distances from the gated surface. Thus, the mechanism underlying this process is of considerable interest. Here we directly image, using in situ, real-time, high-resolution transmission electron microscopy, the reversible transformation between the oxygen vacancy ordered phase brownmillerite SrCoO and the oxygen ordered phase perovskite SrCoO. We show that the phase transformation boundary moves at a velocity that is highly anisotropic, traveling at speeds ~30 times faster laterally than through the thickness of the film. Taking advantage of this anisotropy, we show that three-dimensional metallic structures such as cylinders and rings can be realized. Our results provide a roadmap to the construction of complex meso-structures from their exterior surfaces.
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http://dx.doi.org/10.1038/s41467-018-05330-1 | DOI Listing |
RSC Adv
December 2024
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Beryllium carbonate has the highest capacity to bind and release the greenhouse gas CO compared to amines, ionic liquids, CaCO or LiCO. The thermodynamic equilibrium for CO and BeO from BeCO is calculated. TGA of BeCO is used to determine the stepwise mechanism of its CO release, and the low melting point Li/Sr/BeCO is demonstrated.
View Article and Find Full Text PDFWhile zinc-ion and hybrid aqueous battery systems have emerged as potential substitutes for expensive lithium-ion batteries, issues like side reactions, limited electrochemical stability, and electrolyte leakage hinder their commercialization. Due to their low cost, high stability, minimal leakage risks, and a wide variety of modification opportunities, hydrogel electrolytes are considered the most promising solution compared to liquid or solid electrolytes. Here, we synthesized a dual-function hydrogel electrolyte based on polyacrylamide and poly(ethylene dioxythiophene):polystyrene (PPP).
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2024
Department of Applied Chemistry, National Yang Ming Chiao Tung University, Hsinchu, Taiwan 300093.
In recent years, the integration of multifunctional properties into electrospun fabrics has garnered significant attention for applications in wearable devices and smart textiles. A major challenge lies in achieving a balance among intermolecular interactions, structural stability, and responsiveness to external stimuli. In this study, we address this challenge by developing intrinsically healable and photoresponsive electrospun fabrics composed of poly(vinylidene fluoride--hexafluoropropylene) (PVDF-HFP), thermoplastic polyurethane (TPU), and an azobenzene-based ionic liquid ([AzoCMIM][TFSI]).
View Article and Find Full Text PDFChemphyschem
December 2024
Universitat Rostock, Physikalische Chemie, Albert-Einstein-Straße 27, 18059, Rostock, GERMANY.
Glyme-based electrolyte solutions provide new concepts for developing suitable lithium-ion batteries. The so-called solvate ionic liquids (SILs) are promising electrolytes. They are most efficient in equimolar mixtures of lithium bis(trifluoromethanesulfonyl)imide ([Li][NTf2]) and glyme, wherein the [Li]+ cation is supposedly fully solvated by glyme molecules.
View Article and Find Full Text PDFChemistry
December 2024
Guangdong Pharmaceutical University, Guangzhou Higher Education Mega Center, 510006, Guangzhou, CHINA.
Among the various studies on CO2 utilization, the sustainable and cost-effective fixation of CO2 into cyclic carbonates remains one of the most intriguing subjects. To this end, a novel type of composite dicationic ionic liquid material, DIL@PDIL, was developed. This composite consists of a dicationic ionic liquid (DIL), DMAP[TMGH]Br, supported on a polymeric dicationic ionic liquid (PDIL), P-DVB/Im[TMGH]Br.
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