Fourier transform infrared spectroscopy, two-dimensional correlation infrared spectroscopy and principal component analysis were used to discriminate seven species of boletus belonging to the same genus. The results showed that the absorption bands of original spectra were similar, which were mainly composed of the absorption bands of protein and polysaccharides, but tiny differences were still observed at the position and intensities of peaks. Two-dimensional correlation infrared spectroscopy technology was applied to study the sample. It showed that there are 6 auto-peaks in the Boletus brunneissimus Chiu and Boletus bicolor, 5 auto-peaks in the Boletus speciosus, 4 auto-peaks in the Boletus griseus Forst and Boletus calopus, only 3 in the Boletus edulis and Boletus aereus in the range of 1 680~1 300 cm-1. The significant differences in the position, intensity of auto-peaks and cross peaks were still observed in the range of 1 680~1 300 cm-1. Same significant differences were observed in the range of 1 150~920 cm-1. Principal component analysis was conducted on boletus with second derivative infrared spectra in the range of 1 800~800 cm-1. All the samples were distinguished and the classification accuracy of principal component analysis is up to 100%. It is demonstrated that Fourier transform infrared spectroscopy combined with two-dimensional correlation infrared spectroscopy or principal component analysis is a rapid and effective method for discriminating mushrooms.
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Sci Rep
January 2025
Geology Department, Faculty of Science, Assiut University, Assiut, Egypt.
Limestone mining waste and its derived CaO were checked as an adsorbents of pb, Cu, and Cd ions from water solution. The characterization of Limestone and calcined limestone was studied by using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), Scanning Electron Microscope (SEM), and Surface area measurements (BET). The optimum conditions of sorbent dosage, pH, initial concentration, and contact time factors were investigated for pristine limestone and calcined limestone absorbents.
View Article and Find Full Text PDFTransl Psychiatry
January 2025
Department of Biomedical Engineering, National University of Singapore, Singapore, Singapore.
Environ Pollut
January 2025
College of Land Resources and Environment, Jiangxi Agricultural University, Nanchang, 330045, P.R. China.
Propyrisulfuron, a novel sulfonylurea herbicide, effectively suppresses intracellular acetolactate synthase activity for weed control, but its adsorption behavior in the soil environment remains unclear. To assess potential agroecosystem risks, the adsorption-desorption behavior and mechanism of propyrisulfuron in six typical agricultural soils of China were investigated using a batch equilibrium method, Density Functional Theory (DFT), Fourier Transform Infrared Spectroscopy (FTIR), and Scanning Electron Microscopy equipped with Energy Dispersive X-ray (SEM-EDX) techniques. It is indicated that the adsorption-desorption of propyrisulfuron in six soils reached equilibrium at 36 hours under the optimum water-to-soil ratio (WSr) of 5:1.
View Article and Find Full Text PDFInt J Pharm
January 2025
Department of Pharmacy, Faculty of Health and Medical Sciences, University of Copenhagen 2100 Copenhagen, Denmark. Electronic address:
Additively manufactured drug products, typically produced using small-scale, on-demand batch mode, require rapid and non-destructive quantification methods. A tunable modular design (TMD) approach combining porous polymeric freeze-dried modules and an additive manufacturing method, inkjet printing, was proposed in an earlier study to fabricate accurate and patient-tailored doses of an antidepressant citalopram hydrobromide. This approach addresses the unmet medical needs associated with antidepressant tapering.
View Article and Find Full Text PDFWater Res
January 2025
China Electronics System Engineering No.2 Construction Co., Ltd., Wuxi 214115, PR China.
Copper-containing industrial wastewater, characterized by strong acidity, high ionic strength, and various competing metals, presents significant challenges for Cu(II) recovery. To address these issues, an electric field-enhanced ultrafiltration process was developed, assisted with a functional polyelectrolyte with high selectivity for Cu(II). The polyelectrolyte, termed PPEI, was synthesized by grafting picolyl groups onto polyethyleneimine (PEI), enhancing its affinity for Cu(II).
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